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543047

Sigma-Aldrich

Deuterium chloride solution

35 wt. % in D2O, ≥99 atom % D

Synonym(s):

Hydrochloric acid-d solution

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About This Item

Linear Formula:
DCl
CAS Number:
7698-05-7
Molecular Weight:
37.47
MDL number:
MFCD00044642
UNSPSC Code:
12352106
PubChem Substance ID:
24878657
NACRES:
NA.12

isotopic purity

≥99 atom % D

concentration

35 wt. % in D2O

technique(s)

NMR: suitable

mass shift

M+1

SMILES string

Cl[2H]

InChI

1S/ClH/h1H/i/hD

InChI key

VEXZGXHMUGYJMC-DYCDLGHISA-N

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General description

Lithium deuteride is isotopically labeled analogue of Lithium hydride.

Application

Deuterium chloride solution has been used to study:
  • The kinetics of chitosan reacetylation using acetic anhydride and acetic acid.
  • Regioselective terminal group activation of chitosan by thioacetylation.
  • The complex formation between cyclodextrin and captopril in aqueous solution using NMR spectroscopy.

Lithium deuteride can act as semiconductor at 30GPa and room temperature. It is used as the polarized deuteron target material for the measurement of proton and neutron structure

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Jean Lesne et al.
Nature communications, 11(1), 6140-6140 (2020-12-03)
Hydrogen-Deuterium eXchange coupled to Mass Spectrometry (HDX-MS) is now common practice in structural biology. However, it is most of the time applied to rather small oligomeric complexes. Here, we report on the use of HDX-MS to investigate conformational differences between
Inclusion complex formation of captopril with $\alpha$-and $\beta$-cyclodextrins in aqueous solution: NMR spectroscopic and molecular dynamic studies.
Ikeda Y, et al.
Journal of Pharmaceutical Sciences, 91(11), 2390-2398 (2002)
Kinetics and efficiency of chitosan reacetylation.
Lavertu M, et al.
Carbohydrate Polymers, 87(2), 1192-1198 (2012)
Regioselective chitosan end-group activation: the triskelion approach
Pickenhahn VD, et al.
Royal Society of Chemistry Advances, 7(30), 18628-18638 (2017)
Andrey N Pravdivtsev et al.
PloS one, 15(10), e0239982-e0239982 (2020-10-02)
Magnetic resonance spectroscopy (MRS) allows the analysis of biochemical processes non-invasively and in vivo. Still, its application in clinical diagnostics is rare. Routine MRS is limited to spatial, chemical and temporal resolutions of cubic centimetres, mM and minutes. In fact
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