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542792

Sigma-Aldrich

2-Pyridylamidoxime

97%

Synonym(s):

N-Hydroxypyridine-2-carboxamidine

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About This Item

Empirical Formula (Hill Notation):
C6H7N3O
CAS Number:
1772-01-6
Molecular Weight:
137.14
MDL number:
MFCD00085159
UNSPSC Code:
12352100
PubChem Substance ID:
24878634
NACRES:
NA.22

assay

97%

mp

120-124 °C (lit.)

SMILES string

N\C(=N/O)c1ccccn1

InChI

1S/C6H7N3O/c7-6(9-10)5-3-1-2-4-8-5/h1-4,10H,(H2,7,9)

InChI key

XKXCGXSHUNVFCT-UHFFFAOYSA-N

Packaging

2-Pyridylamidoxime (PAO) is a pyridine derivative. It undergoes reaction with the following complexes:
  • [Cr(CO)6] in THF to afford tris derivative [Cr(PAO)3]
  • [Cr(CO)6] in the presence of bipyridine (bpy) to form the binuclear complex [Cr2O4(PAO)(bpy)]
  • [Mo(CO)6] in air to give [Mo2O6(PAO)2]
  • [Mo(CO)6] in the presence of bpy to yield the isomeric forms of [Mo(CO)4(PAO)].bpy

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Novel Chromium, Molybdenum, and Tungsten Complexes of 2-pyridylamidoxime.
Shohayeb SM, et al.
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 40(10) (2010)

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