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Sigma-Aldrich

Tetraammineplatinum(II) nitrate

99.995% trace metals basis

Synonym(s):

Platinum tetraamine dinitrate, Tetraamineplatinum(II) dinitrate, Tetraamminedinitratoplatinum

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About This Item

Linear Formula:
[Pt(NH3)4](NO3)2
CAS Number:
20634-12-2
Molecular Weight:
387.21
EC Number:
243-929-9
MDL number:
MFCD00011624
UNSPSC Code:
12161600
PubChem Substance ID:
24871708
NACRES:
NA.22

assay

99.995% trace metals basis

form

solid

reaction suitability

core: platinum
reagent type: catalyst

mp

262 °C (dec.) (lit.)

SMILES string

N.N.N.N.[Pt++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.4H3N.Pt/c2*2-1(3)4;;;;;/h;;4*1H3;/q2*-1;;;;;+2

InChI key

RBAKORNXYLGSJB-UHFFFAOYSA-N

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Application

Tetraammineplatinum(II) nitrate can be used as a platinum (Pt) precursor to synthesize platinum-based catalysts such as Pt/cerium oxide catalysts and Pt/mesoporous carbon catalysts. It is also used in synthesizing lean NOx trap (LNT) catalysts.

pictograms

Exploding Bomb
GHS01

signalword

Danger

hcodes

H240,H412

Hazard Classifications

Aquatic Chronic 3 - Org. Perox. A

supp_hazards

EUH044

Storage Class

4.1A - Other explosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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NOx storage and reduction properties of model ceria-based lean NOx trap catalysts.
Shi C, et al.
Applied Catalysis. B, Environmental, 119, 183-196 (2012)
Preparation of Pt/mesoporous carbon (MC) electrode catalyst and its reactivity toward oxygen reduction.
Hayashi A, et al.
Electrochimica Acta, 53(21), 6117-6125 (2008)
L X Yang et al.
International journal of radiation biology, 68(6), 609-614 (1995-12-01)
Carboplatin (3.6 mM) and salmon sperm DNA (3 micrograms), either double-stranded (dsDNA) or denatured single-stranded) (ssDNA), were irradiated (100 Gy) under hypoxic or oxic conditions. The drug and DNA were mixed either before, during, or after irradiation, and platinum binding
High performance monolithic catalysts for hydrogenation reactions.
Perez-Cadenas A F, et al.
Catalysis Today, 105(3-4), 623-628 (2005)
Austin B Yongye et al.
Journal of computer-aided molecular design, 24(3), 225-235 (2010-03-25)
The potential energy surfaces of chiral tetraamine Pt(II) coordination complexes were computed at the B3LYP/LANL2DZ level of theory by a systematic variation of two dihedral angles: C12-C15-C34-C37 (theta) and C24-C17-C31-C48 (psi) employing a grid resolution of 30 degrees . Potential
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