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476420

Sigma-Aldrich

Dimethyl allylmalonate

98%

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25 ML
$108.30

$108.30

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25 ML
$108.30

About This Item

Linear Formula:
H2C=CHCH2CH(CO2CH3)2
CAS Number:
40637-56-7
Molecular Weight:
172.18
EC Number:
255-017-8
MDL number:
MFCD00014959
UNSPSC Code:
12352100
PubChem Substance ID:
24871252
NACRES:
NA.22

$108.30

List Price$114.00Save 5%
Web-Only Promotion

Available to ship onApril 29, 2025Details

Request a Bulk Order

Quality Level

100

assay

98%

refractive index

n20/D 1.435 (lit.)

bp

207 °C/771 mmHg (lit.)

density

1.071 g/mL at 25 °C (lit.)

functional group

allyl
ester

SMILES string

COC(=O)C(CC=C)C(=O)OC

InChI

1S/C8H12O4/c1-4-5-6(7(9)11-2)8(10)12-3/h4,6H,1,5H2,2-3H3

Inchi Key

VZNFVLWVVHHMBG-UHFFFAOYSA-N

Related Categories

Application

Dimethyl allylmalonate may be used in the preparation of:
  • terminal alkyl silane[1]
  • diallyl malonates[2]
  • bromosulfoxide[3]
  • dimethyl-2-allyl-2-{4-methyl-2-[(tetrahydro-2H-pyran-2-yloxy)methyl]deca-2,3-dienoyl}malonate[4]

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

199.4 °F - closed cup

flash_point_c

93 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
07112CJ
10523EO
03311EO
08317JR
S05599

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Synthesis of substituted cyclopentenes from the Baylis-Hillman adducts via ring-closing metathesis reaction.
Lee KY, et al.
Bull. Korean Chem. Soc., 25(8), 1280-1282 (2004)
The study of intramolecular free radical cyclizations of a-sulfonyl and a-sulfinyl radicals.
Yeun-Min T, et al.
Tetrahedron Letters, 31(42), 6047-6050 (1990)
Tandem cyclization/hydrosilylation of functionalized 1, 6-dienes catalyzed by a cationic palladium complex.
Widenhoefer RA and DeCarli MA.
Journal of the American Chemical Society, 120(15), 3805-3806 (1998)
Krause N.
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 138-138 (2014)

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