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427128

Sigma-Aldrich

Gallium(III) chloride

anhydrous, beads, ≥99.999% trace metals basis

Synonym(s):

Gallium trichloride

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About This Item

Linear Formula:
GaCl3
CAS Number:
13450-90-3
Molecular Weight:
176.08
EC Number:
236-610-0
MDL number:
MFCD00011018
UNSPSC Code:
12352302
PubChem Substance ID:
24866737
NACRES:
NA.23
assay:
≥99.999% trace metals basis
grade:
anhydrous
form:
beads

grade

anhydrous

Quality Level

200

vapor pressure

1 mmHg ( 48 °C)

assay

≥99.999% trace metals basis

form

beads

reaction suitability

reagent type: catalyst
core: gallium

impurities

≤10.0 ppm Trace Metal Analysis

mp

78 °C (lit.)

density

2.47 g/mL at 25 °C (lit.)

SMILES string

Cl[Ga](Cl)Cl

InChI

1S/3ClH.Ga/h3*1H;/q;;;+3/p-3

InChI key

UPWPDUACHOATKO-UHFFFAOYSA-K

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General description

Gallium(III) chloride is prepared by reacting Ga metal with Cl2 or HCl in N2 at 200oC.1

Application

Catalyst for a number of transformations such as the ring opening and recyclization of epoxides or the trimerization of alkynes.[1][2]

Features and Benefits

Lower-temperature solvothermal techniques using GaCl3 and NaN3 or Li3N result in nanocrystalline GaN.
Radical mediator and catalyst in a number of organic bond formation reactions.

Packaging

product is packed in vials

accessory

Product No.
Description
Pricing

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

supp_hazards

EUH014

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCK3733
SHBL0939
042619AM
MKBZ5943V
MKCB9165

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Indium(III) chloride

Chien-Hui Syu et al.
The Science of the total environment, 759, 143943-143943 (2020-12-20)
The emerging contaminants gallium (Ga) and indium (In) are extensively used in advanced industries and are considered as toxic to humans. Limited information is available on the dynamics of Ga and In in soil-upland crop systems. Therefore, this study aimed
Barman, D.C.
Synlett, 2440-2440 (2003)
Amir R Jalilian et al.
Acta pharmaceutica (Zagreb, Croatia), 59(4), 421-429 (2009-11-19)
beta-Human chorionic gonadotropin (beta-hCG) was successively labeled with [(67)Ga]-gallium chloride after conjugation with freshly prepared diethylenetriaminepentaacetic acid dianhydride (ccDTPA). After solid phase purification of the radiolabeled hormone, high performance liquid chromatography showed radiochemical purity higher than 95 % under optimized
C Caraco et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 49(12), 1477-1479 (1998-09-24)
Previous studies report that deferoxamine (DFO) binds metallic ions such as Fe3+, In3+ and Ga3+ with very high affinity. This property of DFO has been utilized to label DFO-coupled compounds with radiometals such as 67Ga and 111In. We have studied
Tiina Ujula et al.
Molecular imaging and biology : MIB : the official publication of the Academy of Molecular Imaging, 12(3), 259-268 (2009-10-03)
The aim of the study was to compare (68)Ga-chloride with 2-[(18)F]fluoro-2-deoxy-D: -glucose (FDG) for the imaging of pancreatic xenografts. Rats with subcutaneous human pancreatic adenocarcinoma xenografts were evaluated in vivo by dynamic positron emission tomography (PET) and ex vivo by
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