416673

Bis(cyclopentadienyl)zirconium(IV) bis(trifluoromethanesulfonate)tetrahydrofuran complex

97%

• Synonym(s): Bis(cyclopentadienyl)zirconium(IV) bis(trifluoromethanesulfonate) THF complex, Di(cyclopentadienyl)zirconium(IV) bis(trifluoromethanesulfonate) THF complex, Zirconocene bis(trifluoromethanesulfonate) THF complex
• Empirical Formula (Hill Notation): C₁₂H₁₀F₆O₆S₂Zr · C₄H₈O
• CAS Number: 89672-77-5
• Molecular Weight: 591.65
• MDL number: MFCD00192583
• UNSPSC Code: 12161600
• PubChem Substance ID: 24865920
• NACRES: NA.22

Properties

• assay: 97%
• reaction suitability: core: zirconium; reagent type: catalyst
• SMILES string: [Zr++].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.C3CCOC3.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
• InChI: 1S/2C5H5.C4H8O.2CHF3O3S.Zr/c3*1-2-4-5-3-1;2*2-1(3,4)8(5,6)7;/h2*1-5H;1-4H2;2*(H,5,6,7);/q;;;;;+2/p-2
• InChI key: OFTAVORSNHLQHT-UHFFFAOYSA-L

Description

Application

Reagent for synthesis of β-hFSH with Chitobiose units

Reactant for polyoxometalate transfer for synthesis of zirconocene polyoxometalate

Transition metal based Lewis acid catalyst

Catalyst for:

• Mukaiyama cross-aldol reactions
• Diels-Alder reactions

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: 174.2 °F - closed cup
• flash_point_c: 79 °C - closed cup
• ppe: dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges