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409774

Sigma-Aldrich

Trimethylolpropane ethoxylate

average Mn ~450

Synonym(s):

3 arm PEG, 3 arm PEO, Poly(ethylene oxide), 3-arm, hydroxy terminated, Polyethylene glycol trimethylolpropane ether, Polyethylene glycol trimethylolpropane triether, Trimethylolpropane ethoxylate (20/3 EO/OH), Trimethylolpropane ethoxylate (4.6 EO/OH), Trimethylolpropane ethoxylate (4/15 EO/OH)

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About This Item

Linear Formula:
(C2H4O)n(C2H4O)n(C2H4O)nC6H14O
CAS Number:
50586-59-9
MDL number:
MFCD00197947
UNSPSC Code:
12162002

mol wt

average Mn ~450

refractive index

n20/D 1.472

density

1.114 g/mL at 25 °C

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Application

Trimethylolpropane ethoxylate (TMPE) can be dissolved with lithium trifluoromethanesulfonate (LiCF3SO3) to form an electrolyte. These electrolytes can act as charge transferring mediums for light emitting electrochemical cells and devices.[1][2][3][4]

Storage Class

10 - Combustible liquids

wgk_germany

WGK 1

flash_point_f

444.2 °F - closed cup

flash_point_c

229 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKBG4218V
06530DF

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Quest for an appropriate electrolyte for high-performance light-emitting electrochemical cells
Tang S and Edman L
The Journal of Physical Chemistry Letters, 1(18), 2727-2732 (2010)
Identifying key properties of electrolytes for light-emitting electrochemical cells
Tang S, et al.
Chemistry of Materials, 26(17), 5083-5088 (2014)
White light from a single-emitter light-emitting electrochemical cell
Tang S, et al.
Journal of the American Chemical Society, 135(9), 3647-3652 (2013)
Small-molecule light-emitting electrochemical cells: evidence for in situ electrochemical doping and functional operation
Tang S, et al.
Chemical Communications (Cambridge, England), 49(43), 4926-4928 (2013)

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