Skip to Content
MilliporeSigma
All Photos(3)

Documents

407739

Sigma-Aldrich

L-tert-Leucinol

98%, for peptide synthesis

Synonym(s):

(S)-2-Amino-3,3-dimethyl-1-butanol

Sign Into View Organizational & Contract Pricing
All Photos(3)

About This Item

Linear Formula:
(CH3)3CCH(NH2)CH2OH
CAS Number:
112245-13-3
Molecular Weight:
117.19
Beilstein/REAXYS Number:
3600321
MDL number:
MFCD00192250
UNSPSC Code:
12352209
PubChem Substance ID:
24865483
NACRES:
NA.22

product name

L-tert-Leucinol, 98%

assay

98%

optical activity

[α]26/D +37°, c = 1.5 in ethanol

reaction suitability

reaction type: solution phase peptide synthesis

mp

30-34 °C (lit.)

density

0.9 g/mL at 25 °C (lit.)

application(s)

peptide synthesis

SMILES string

CC(C)(C)[C@H](N)CO

InChI

1S/C6H15NO/c1-6(2,3)5(7)4-8/h5,8H,4,7H2,1-3H3/t5-/m1/s1

InChI key

JBULSURVMXPBNA-RXMQYKEDSA-N

Looking for similar products? Visit Product Comparison Guide

Application

Useful amino acid employed in various asymmetric reactions.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

194.0 °F - closed cup

flash_point_c

90 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Tetrahedron, 60, 4459-4473 (2004)
Sebastian P Smidt et al.
Organic letters, 6(12), 2023-2026 (2004-06-05)
[reaction: see text] New Ir-SimplePHOX complexes Ir-6-Ir-9 catalyze the quantitative, highly enantioselective hydrogenation of a range of unfunctionalized and functionalized olefins. Synthesis, catalytic results, and X-ray crystal structures are presented here.
Tetrahedron Letters, 45, 5649-5649 (2004)
Heng Wang et al.
Chirality, 27(8), 523-531 (2015-04-25)
A novel pyridineoxazoline (PyOx) containing helical polymer, poly{(-)-(S)-4-tert-butyl-2-[5-(4-tert-butylphenyl)-3-vinylpyridin-2-yl]-oxazoline} (PA), was designed and synthesized to approach the effect of chain conformation on the catalytic property. Its complex with Cu(OTf)(2) , i.e., Cu(II)-PA, was employed to catalyze the homogeneous Diels-Alder (D-A) reaction

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service