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404810

Sigma-Aldrich

N,N′-Bis(3-aminopropyl)-1,3-propanediamine

technical grade, 90%

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About This Item

Linear Formula:
H2N(CH2)3NH(CH2)3NH(CH2)3NH2
CAS Number:
4605-14-5
Molecular Weight:
188.31
EC Number:
225-007-8
MDL number:
MFCD00008213
UNSPSC Code:
12352100
PubChem Substance ID:
24865272
NACRES:
NA.22

grade

technical grade

assay

90%

form

liquid

refractive index

n20/D 1.491 (lit.)

bp

98-103 °C/1 mmHg (lit.)

density

0.92 g/mL at 25 °C (lit.)

SMILES string

NCCCNCCCNCCCN

InChI

1S/C9H24N4/c10-4-1-6-12-8-3-9-13-7-2-5-11/h12-13H,1-11H2

InChI key

ZAXCZCOUDLENMH-UHFFFAOYSA-N

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General description

N,N′-Bis(3-aminopropyl)-1,3-propanediamine, a linear polyamine, has been identified in white shrimp Penaeus setiferus by gas chromatography-mass spectrometry.

Application

N,N′-Bis(3-aminopropyl)-1,3-propanediamine (bappn) may be used in the preparation of [Ni(bappn)(ttcH)]·5H2O complex (ttch= trithiocyanurate dianion).

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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R H Hu et al.
The Biochemical journal, 328 ( Pt 1), 307-316 (1998-01-10)
Treatment of Chinese hamster ovary cells with alpha-difluoromethylornithine for 3 days, followed by exposure to cycloheximide, led to an unregulated, rapid and massive accumulation of polyamine analogues. This accumulation led to cell death by apoptosis within a few hours. Clear
Identification of the unusual polyamines 3,3'-diaminodipropylamine and N,N'-bis(3-aminoproply)-1,3-propanediamine in the white shrimp Penaeus setiferus.
L W Stillway et al.
Biochemical and biophysical research communications, 77(3), 1103-1107 (1977-08-08)
K Hamana et al.
Journal of biochemistry, 91(4), 1321-1328 (1982-04-01)
Seven phyla of eukaryotic algae were analyzed to determine their contents of diamines and polyamines. The algae examined included Rhodophyta, Pyrrophyta, Chrysophyta, Phaeophyta, Euglenophyta, Chlorophyta, and Charophyta. Both putrescine and spermidine were detected in all the algae studied, while appreciable
Anurupa Shrestha et al.
Bioorganic & medicinal chemistry letters, 19(9), 2478-2481 (2009-04-01)
We have previously shown that simple N-acyl or N-alkyl polyamines bind to and sequester Gram-negative bacterial lipopolysaccharide, affording protection against lethality in animal models of endotoxicosis. Several iterative design-and-test cycles of SAR studies, including high-throughput screens, had converged on compounds
Andrew J Geall et al.
Bioconjugate chemistry, 13(3), 481-490 (2002-05-16)
Polyamine amides have been prepared from lithocholic and cholic acids (5beta-colanes) by acylation of tri-Boc-protected tetraamines spermine and thermine. These designed ligands for DNA are polyammonium ions at physiological pH. In NMR spectra, they display 14N-1H 1J = 51 Hz
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