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Key Documents

404349

Sigma-Aldrich

[Bis(trifluoroacetoxy)iodo]pentafluorobenzene

97%

Synonym(s):

FPIFA, Iodopentafluorobenzene bis(trifluoroacetate)

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About This Item

Linear Formula:
(CF3CO2)2IC6F5
CAS Number:
Molecular Weight:
519.99
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22

assay

97%

reaction suitability

reagent type: oxidant

mp

117-119 °C (lit.)

SMILES string

Fc1c(F)c(F)c([I](OC(=O)C(F)(F)F)OC(=O)C(F)(F)F)c(F)c1F

InChI

1S/C10F11IO4/c11-1-2(12)4(14)6(5(15)3(1)13)22(25-7(23)9(16,17)18)26-8(24)10(19,20)21

InChI key

OQWAXRPJEPTTSZ-UHFFFAOYSA-N

Application

Reactant or reagent for:
  • Oxidation of organic iodides using oxone and trifluoroacetic acid
  • Base hydrolysis
  • Oxidative cross-coupling of arenes
  • Oxidation of phenolic compounds with organohypervalent iodine
  • Aziridination of alkenes
  • Oxidation of organic compounds
  • Oxidative fragmentation of α-amino acids or β-amino alcohols
  • Oxidative biaryl coupling of thiophenes

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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