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38894

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide

≥98.0% (T)

Synonym(s):

BMP-BTI

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$171.00

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$578.00

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About This Item

Empirical Formula (Hill Notation):
C11H20F6N2O4S2
CAS Number:
Molecular Weight:
422.41
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
≥98.0% (T)

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InChI

1S/C9H20N.C2F6NO4S2/c1-3-4-7-10(2)8-5-6-9-10;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h3-9H2,1-2H3;/q+1;-1

SMILES string

CCCC[N+]1(C)CCCC1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI key

HSLXOARVFIWOQF-UHFFFAOYSA-N

description

electrochemical window -3.0 - +2.4 V

assay

≥98.0% (T)

impurities

≤0.2% water

viscosity

548 stokes

mp

-18 °C

functional group

fluoro

Quality Level

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General description

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide is a room temperature ionic liquid (RTIL) with a wide electrochemical window (5.5V) and high viscosity, making it a useful candidate in electrochemical energy applications.

Application

BMP-BTI has been used as a derivatization media for dimethyl sulfate (DMS) with dibenzazepine.[1]

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Ionic Liquids for Energy Storage Applications
Stenger-Smith JD and Irvin JA.
Material Matters, 4(4), 103-103 (2009)
Electrodeposition of al in 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) amide and 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) amide ionic liquids: In situ STM and EQCM studies
Moustafa, E. M., et al.
The Journal of Physical Chemistry B, 111.18, 4693-4704 (2007)
Voltammetric Study and Electrodeposition of Zinc in Hydrophobic Room-Temperature Ionic Liquid 1-Butyl-1-methylpyrrolidinium Bis ((trifluoromethyl) sulfonyl) imide ([BMP][TFSI]): A Comparison between Chloride and TFSI Salts of Zinc
Wang, Yu-Sheng, et al.
Journal of the Electrochemical Society, 164.2, D39-D47 (2017)
Study of the formation process and the characteristics of tantalum layers electrodeposited on Nitinol plates in the 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide ionic liquid
Maho, Anthony, Joseph Delhalle, and Zineb Mekhalif
Electrochimica Acta, 89, 346-358 (2013)
An ionic liquid based strain sensor for large displacement measurement
Keulemans, Grim, Frederik Ceyssens, and Robert Puers
Biomedical Microdevices, 19.1, 1-1 (2017)

Articles

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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