364886

(R)-(−)-1-Benzyloxy-3-(p-tosyloxy)-2-propanol

95%

• Synonym(s): (R)-(−)-1-Benzyloxy-3-tosyloxy-2-propanol, (R)-(−)-3-Benzyloxy-1,2-propanediol 1-(p-toluenesulfonate), 1-Benzyl-sn-glycerol 3-tosylate
• Linear Formula: CH₃C₆H₄SO₃CH₂CH(OH)CH₂OCH₂C₆H₅
• CAS Number: 23214-66-6
• Molecular Weight: 336.40
• MDL number: MFCD00134285
• UNSPSC Code: 12352108
• PubChem Substance ID: 24862464
• NACRES: NA.22

Properties

• assay: 95%
• optical activity: [α]25/D −7°, c = 10 in toluene
• mp: 52-55 °C (lit.)
• functional group: ether; hydroxyl; phenyl; tosylate
• SMILES string: Cc1ccc(cc1)S(=O)(=O)OC[C@H](O)COCc2ccccc2
• InChI: 1S/C17H20O5S/c1-14-7-9-17(10-8-14)23(19,20)22-13-16(18)12-21-11-15-5-3-2-4-6-15/h2-10,16,18H,11-13H2,1H3/t16-/m1/s1
• InChI key: HBMUWOSOGHUWSS-MRXNPFEDSA-N

Description

Application

Reagent employed in enantioselective carbohydrate, terpene, and alkaloid syntheses.[1]

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: 230.0 °F - closed cup
• flash_point_c: 110 °C - closed cup
• ppe: Eyeshields, Gloves, type N95 (US)