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334642

Sigma-Aldrich

Bis(cyclopentadienyl)vanadium(IV) dichloride

95%

Synonym(s):

Di-π-Cyclopentadienylvanadium dichloride, Dichlorobis(cyclopentadienyl)vanadium, Dichlorovanadocene, Vanadocene dichloride

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About This Item

Empirical Formula (Hill Notation):
C10H10Cl2V
CAS Number:
12083-48-6
Molecular Weight:
252.03
EC Number:
235-150-8
MDL number:
MFCD00014260
UNSPSC Code:
12352300
PubChem Substance ID:
24860247

assay

95%

form

solid

reaction suitability

core: vanadium
reagent type: catalyst

storage temp.

2-8°C

SMILES string

Cl[V]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.2ClH.V/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChI key

MDWJZZZKWHLMQP-UHFFFAOYSA-L

Application

Uses:
  • Potential pharmacological compound for cancer treatment
  • Catalyst for solvent free, room temperature preparation of vicinal aminoalcohols as fungistatic agents
  • Catalyst fot oligomerization reactions via the Aufbau propagation reaction
  • Catalyst for aqueous polymerization reactions using oxygen as a cocatalyst
  • Catalyst for dl-selective pinacol-type coupling reactions
  • Affector of crystal growth of calcium carbonate
  • Inhibitor of human topoisomerase II enzyme with antitumor activity

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKBV5933V
MKBR4487V
MKBN8741V
MKBK6123V
MKBD4266

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J H Toney et al.
Chemico-biological interactions, 56(1), 45-54 (1985-12-17)
The biodistribution and pharmacokinetics of vanadium following i.p. administration of vanadocene dichloride (VDC), a representative of a new class of organometallic anticancer agents, is reported for Strain A mice. A convenient flameless atomic absorption spectroscopic assay is described and is
P Köpf-Maier
Journal of cancer research and clinical oncology, 103(2), 145-164 (1982-01-01)
Light-microscopic and ultrastructural alteration patterns are investigated after in vivo treatment of EAT with the cytostatic agents VDC and TC. Both substances induce mitotic aberrations, e.g., pyknotic metaphases, lagging chromosomes during anaphase, and multipolar mitotic figures. The appearance of mononucleate
P Köpf-Maier et al.
Chemico-biological interactions, 44(3), 317-328 (1983-06-01)
The intracellular distribution patterns of the metal atoms titanium and vanadium after in vivo as well as in vitro treatment of Ehrlich ascites tumor with the antitumor agents titanocene dichloride (TDC) or vanadocene dichloride (VDC) have been investigated by use
O J D'Cruz et al.
Biology of reproduction, 58(6), 1515-1526 (1998-06-12)
We have used computer-assisted sperm analysis (CASA) to evaluate the spermicidal activity of 8 metallocene dihalides (vanadocene dichloride [VDC], titanocene dichloride [TDC], zirconocene dichloride [ZDC], molybdocene dichloride [MDC], hafnocene dichloride [HDC], vanadocene dibromide [VDB], bis[methylcyclopentadienyl] vanadium dichloride [VMDC], and vanadocene
Jan Honzícek et al.
Magnetic resonance in chemistry : MRC, 48(7), 562-564 (2010-06-11)
The reaction of vanadocene dichloride with sodium arsenate gives Cp(2)V(O(2)AsO(2)H). This compound was identified on the basis of the super-hyperfine coupling observed in the solution EPR spectrum. The effect of substitution was studied on the ring-substituted and ansa-bridged compounds.
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