297801

Methyl 2-amino-3,5-dibromobenzoate

98%

• Synonym(s): Methyl 3,5-dibromoanthranilate
• Linear Formula: Br₂C₆H₂-2-(NH₂)CO₂CH₃
• CAS Number: 606-00-8
• Molecular Weight: 308.95
• MDL number: MFCD00010873
• UNSPSC Code: 12352100
• PubChem Substance ID: 24857930

Properties

• assay: 98%
• mp: 89-91 °C (lit.)
• SMILES string: COC(=O)c1cc(Br)cc(Br)c1N
• InChI: 1S/C8H7Br2NO2/c1-13-8(12)5-2-4(9)3-6(10)7(5)11/h2-3H,11H2,1H3
• InChI key: NGXVMFCGYYHEGC-UHFFFAOYSA-N

Description

General description

Methyl 2-amino-3,5-dibromobenzoate participates in cobalt(II) Schiff′s base complex catalyzed oxidation of primary and secondary alcohols to aldehydes and ketones respectively. It also participates in allylic and benzylic oxidation of various cyclic alkenes and benzylic compounds respectively.

Application

Methyl 2-amino-3,5-dibromobenzoate was used in the preparation of ethyl 1-(p-methoxyphenyl)-2-oxocyclopentanecarboxylate via reaction with chloroform containing pyridine.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves