253111

Borane N,N-diisopropylethylamine complex

• Synonym(s): Diisopropylethylamine borane
• Linear Formula: [(CH₃)₂CH]₂NC₂H₅·BH₃
• CAS Number: 88996-23-0
• Molecular Weight: 143.08
• MDL number: MFCD00013185
• UNSPSC Code: 12352116
• PubChem Substance ID: 24855263
• NACRES: NA.22

Properties

• reaction suitability: reagent type: reductant
• refractive index: n20/D 1.46 (lit.)
• mp: 15-17 °C (lit.)
• density: 0.822 g/mL at 25 °C (lit.)
• SMILES string: B.CCN(C(C)C)C(C)C
• InChI: 1S/C8H19N.BH3/c1-6-9(7(2)3)8(4)5;/h7-8H,6H2,1-5H3;1H3
• InChI key: DWXQHSSGDGWIMP-UHFFFAOYSA-N

Description

Application

Reactant for:

• Preparation of modifiable bidentate systems via nitrogen-carbon rearrangement
• Preparation of bioactive boranophosphonic acids
• Preparation of precursors for synthesis of boronated oligonucleotide sequences
• Synthesis of dithymidine boranophosphate via the oxathiaphospholane approach
• Preparation of adenosine boranothiotriphosphate ribonucleoside and thymidine boranothiotriphosphate deoxyribonucleoside
• Preparation of borane-amine complexes

Safety Information

• pictograms: GHS02,GHS05
• signalword: Danger
• hcodes: H226,H314
• pcodes: P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Flam. Liq. 3 - Skin Corr. 1B
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 104.0 °F - closed cup
• flash_point_c: 40 °C - closed cup
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter