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202231

Sigma-Aldrich

Chromium(III) acetylacetonate

97%

Synonym(s):

Chromium(III) 2,4-pentanedionate, Cr(acac)3

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About This Item

Linear Formula:
Cr(C5H7O2)3
CAS Number:
Molecular Weight:
349.32
Beilstein/REAXYS Number:
4148971
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

assay

97%

form

solid

reaction suitability

core: chromium

bp

340 °C (lit.)

mp

210 °C (lit.)

SMILES string

CC(=O)\C=C(\C)O[Cr](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Cr/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

JWORPXLMBPOPPU-LNTINUHCSA-K

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Application

  • Redox-Activity Catalysis: Discusses the ligand field-activated redox activity of Chromium(III) acetylacetonate, highlighting its use in hydrogenation catalysis (Vinum et al., 2020).
  • Diffusion Behavior in Supercritical CO2: A study examining the diffusion behavior of Chromium(III) acetylacetonate in supercritical CO2, aiding in the application of supercritical fluids in materials processing (Cordeiro et al., 2016).

Analysis Note

Used to modify the surface properties of solid polyurethanes formed in its presence.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

>392.0 °F

flash_point_c

> 200 °C

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Michael E Ziebel et al.
Chemical science, 11(26), 6690-6700 (2020-09-22)
The incorporation of second-row transition metals into metal-organic frameworks could greatly improve the performance of these materials across a wide variety of applications due to the enhanced covalency, redox activity, and spin-orbit coupling of late-row metals relative to their first-row
Channa R De Silva et al.
Journal of the American Chemical Society, 131(18), 6336-6337 (2009-04-17)
Nearly monodisperse lanthanide-doped magnetite nanoparticles were obtained by thermally decomposing a mixture of Fe(acac)(3) and Ln(acac)(3) (acac = acetylacetonate; Ln = Sm, Eu, Gd) in the presence of passivating surfactants. Magnetic studies revealed room-temperature ferromagnetic behaviors of these doped nanoparticles
Nathan A Mathew et al.
The journal of physical chemistry. A, 114(2), 817-832 (2009-12-03)
Nuclear magnetic resonance spectroscopy relies on using multiple excitation pulses to create multiple quantum coherences that provide great specificity for chemical measurements. Coherent multidimensional spectroscopy (CMDS) is the optical analogue of NMR. Current CMDS methods use three excitation pulses and
Zhan'ao Tan et al.
Physical chemistry chemical physics : PCCP, 14(42), 14589-14595 (2012-09-28)
A solution-processed vanadium oxide (s-VO(x)) anode buffer layer on an indium-tin-oxide (ITO) electrode was used instead of PEDOT:PSS for improving the stability and photovoltaic performance of the polymer solar cells (PSCs). The s-VO(x) layer was prepared by spin-coating a vanadyl
Nan Tian et al.
Dalton transactions (Cambridge, England : 2003), 39(37), 8613-8615 (2010-08-19)
The design, synthesis, photophysical and significantly improved electrooptical properties of a series of red emitting cyclometalated iridium(iii) complexes containing carbazolyl-acetylacetonate ligands are described.

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