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14889

Sigma-Aldrich

2,2′-(4-Methylphenylimino)diethanol

≥97.0% (NT)

Synonym(s):

2,2′-(p-Tolylimino)diethanol, N,N-Bis(2-hydroxyethyl)-p-toluidine, N-(p-Tolyl)diethanolamine

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About This Item

Linear Formula:
CH3C6H4N(CH2CH2OH)2
CAS Number:
Molecular Weight:
195.26
Beilstein/REAXYS Number:
2099156
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

≥97.0% (NT)

form

solid

bp

338-340 °C (lit.)

mp

49-53 °C (lit.)

SMILES string

Cc1ccc(cc1)N(CCO)CCO

InChI

1S/C11H17NO2/c1-10-2-4-11(5-3-10)12(6-8-13)7-9-14/h2-5,13-14H,6-9H2,1H3

InChI key

JUVSRZCUMWZBFK-UHFFFAOYSA-N

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Application

2,2′-(4-Methylphenylimino)diethanol (p-tolyl diethanolamine) was used as an activating amine.

Caution

may discolor to brown on storage

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

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M P Patel et al.
Biomaterials, 12(7), 649-652 (1991-09-01)
A number of useful room temperature polymerizing resins were formulated, based on poly(ethyl methacrylate) powder and a range of low shrinkage heterocyclic methacrylate monomers. N,N-dimethyl-p-toluidine or p-tolyl diethanolamine were used as activating amines, but the latter material is less active
L Kanerva et al.
Acta dermato-venereologica, 73(2), 126-129 (1993-04-01)
Dental personnel are exposed to many sensitizing compounds at work and often develop multiple delayed allergies. Here we report on a dentist who got sensitized to several products that have not, or only seldom, caused sensitization earlier. These products were:
M Jontell et al.
Journal of dental research, 74(5), 1162-1167 (1995-05-01)
Monomeric resin components from dental composites are toxic to fibroblasts in culture and thus may interfere with the local immune system of the pulp, reducing its effective defense potential, either by cytotoxicity or by a more specific immune mechanism. Therefore
Ulrich Salz et al.
The journal of adhesive dentistry, 7(1), 7-17 (2005-05-17)
To investigate the influence of the acid-base reaction between acidic monomers and amines on the polymerization behavior of self-etching, self-curing adhesives, determine the effect of the application mode on the shear bond strength and morphology, and elucidate the adhesion performance
K Ikemura et al.
Dental materials journal, 15(2), 132-143 (1996-12-01)
To develop a self-etching primer for ground dentin, 4-acryloxyethyltrimellitic acid (4-AET) was newly synthesized, and the effect of concentrations varying from 0 (control) to 56.5 wt% 4-AET in the water/ HEMA primer on bonding to the dentin was investigated. Bond

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