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148245

2-Methoxynaphthalene

Name: 2-Methoxynaphthalene
Brand: ALDRICH

99%

Synonym(s):

Methyl 2-naphthyl ether

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About This Item

Linear Formula:

C₁₀H₇OCH₃

CAS Number:

93-04-9

Molecular Weight:

158.20

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24848894

EC Number:

202-213-6

Beilstein/REAXYS Number:

1859408

MDL number:

MFCD00004061

Assay:

99%

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Properties

assay

99%

bp

274 °C (lit.)

mp

70-73 °C (lit.)

solubility

benzene: soluble, carbon disulfide: soluble, diethyl ether: soluble

density

1.064 g/mL at 25 °C (lit.)

SMILES string

COc1ccc2ccccc2c1

InChI

1S/C11H10O/c1-12-11-7-6-9-4-2-3-5-10(9)8-11/h2-8H,1H3

InChI key

LUZDYPLAQQGJEA-UHFFFAOYSA-N

Gene Information

human ... CYP1A2(1544)

Description

Application

2-methoxynaphthalene acylation was used as a model reaction to study the catalytic benefits of delamination. It was also used to study the alkali-metal-mediated manganation (AMMMn) reactions.

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pictograms

GHS07,GHS09

signalword

Warning

hcodes

H319,H411

pcodes

P264 - P273 - P280 - P305 + P351 + P338 - P337 + P313 - P391

Hazard Classifications

Aquatic Chronic 2 - Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Related Content

FT-NMR Spectra

Spectra - ATR-IR

Spectra for FT-IR Raman

Alkali-metal-mediated manganation(II) of naphthalenes: constructing metalla-anthracene and metalla-phenanthrene structures.

Victoria L Blair et al.

Inorganic chemistry, 48(18), 8863-8870 (2009-09-15)

Alkali-metal-mediated manganation (AMMMn) reactions of the synergic base sodium monoalkyl-bisamidomanganate [(tmeda)Na(tmp)(CH(2)SiMe(3))Mn(tmp)] (1) with naphthalene, 1-methoxynaphthalene, or 2-methoxynaphthalene are reported. These novel direct manganation [Mn(II)] reactions produced the crystalline ortho-manganated naphthyl products [(tmeda)Na(tmp)(2-C(10)H(7))Mn(tmp)] (3), [(tmeda)Na(tmp){2-(1-MeOC(10)H(6))}Mn(CH(2)SiMe(3))] (4), and [(tmeda)Na(tmp){3-(2-MeOC(10)H(6))}Mn(tmp)] (5) in reasonable

Single-step delamination of a MWW borosilicate layered zeolite precursor under mild conditions without surfactant and sonication.

Xiaoying Ouyang et al.

Journal of the American Chemical Society, 136(4), 1449-1461 (2013-12-19)

Layered borosilicate zeolite precursor ERB-1P (Si/B = 11) is delaminated via isomorphous substitution of Al for B using a simple aqueous Al(NO3)3 treatment. Characterization by PXRD shows loss of long-range order, and TEM demonstrates transformation of rectilinear layers in the

Oxidation of 2-methoxynaphthalene by toluene, naphthalene and biphenyl dioxygenases:structure and absolute stereochemistry of metabolites.

G M Whited et al.

Bioorganic & medicinal chemistry, 2(7), 727-734 (1994-07-01)

2-Methoxynaphthalene was subjected to biooxidation by whole cells of six organisms: Pseudomonas putida F39/D containing toluene dioxygenase, Escherichia coli JM109(pDTG601), containing recombinant toluene dioxygenase from Pp F39/D, Pseudomonas sp. NCIB 9816/11, containing naphthalene dioxygenase. E. coli JM109(pDTG141), containing recombinant naphthalene

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Global Trade Item Number

SKU	GTIN
148245-100G	04061838737922