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Sigma-Aldrich

Zinc chloride solution

0.5 M in THF

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About This Item

Linear Formula:
ZnCl2
CAS Number:
7646-85-7
Molecular Weight:
136.30
MDL number:
MFCD00011295
UNSPSC Code:
12352302
PubChem Substance ID:
329755428
NACRES:
NA.55

form

liquid

concentration

0.5 M in THF
470-600 mmol/L (silver nitrate titration)

density

0.948 g/mL at 25 °C

SMILES string

Cl[Zn]Cl

InChI

1S/2ClH.Zn/h2*1H;/q;;+2/p-2

InChI key

JIAARYAFYJHUJI-UHFFFAOYSA-L

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General description

Zinc chloride solution is a colorless liquid that contains zinc chloride dissolved in THF. Its synthesis has been reported.

Application

Zinc chloride solution was used in the synthesis of the ferrocenylarenes.
It may be used for the in situ generation of organozincate reagents by reacting with Grignard compounds and also to catalyze chloromethylation of resins for solid phase peptide synthesis.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-4.0 °F - closed cup

Flash Point(C)

-20 °C - closed cup

Certificates of Analysis (COA)

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Zinc chloride-catalyzed chloromethylation of resins for solid phase peptide synthesis.
Feinberg RS and Merrifield RB.
Tetrahedron, 30(17), 3209-3212 (1974)
Thin-layer electrochemistry of ferrocenylbenzene derivatives: Intramolecular electronic communication.
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Electrochimica Acta, 53(26), 7720-7725 (2008)
Versatile palladium (II)-catalyzed Negishi coupling reactions with functionalized conjugated alkenyl chlorides.
Peyrat JF, et al.
Tetrahedron Letters, 44(35), 6703-6707 (2003)
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