901165
trans-Bis(tricyclohexylphosphine)(2-methylphenyl)nickel(II) chloride
≥95%
Synonym(s):
trans-(PCy3)2Ni(o-tolyl)Cl
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About This Item
Empirical Formula (Hill Notation):
C43H73ClNiP2
CAS Number:
Molecular Weight:
746.13
UNSPSC Code:
12352200
Assay
≥95%
form
powder or solid
reaction suitability
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
mp
>300 °C
SMILES string
Cl[Ni](C1=C(C)C=CC=C1)(P(C2CCCCC2)(C3CCCCC3)C4CCCCC4)P(C5CCCCC5)(C6CCCCC6)C7CCCCC7
Application
The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.
Other Notes
Legal Information
Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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