481432

Cyanogen bromide

99.995% trace metals basis

• Synonym(s): Bromine cyanide
• Linear Formula: BrCN
• CAS Number: 506-68-3
• Molecular Weight: 105.92
• Beilstein: 1697296
• EC Number: 208-051-2
• MDL number: MFCD00011597
• UNSPSC Code: 12352100
• PubChem Substance ID: 24871758
• NACRES: NA.22

Properties

• vapor density: 3.65 (vs air)
• vapor pressure: 100 mmHg ( 22.6 °C)
• Assay: 99.995% trace metals basis
• bp: 61-62 °C (lit.)
• mp: 50-53 °C (lit.)
• functional group: bromo
• storage temp.: 2-8°C
• SMILES string: BrC#N
• InChI: 1S/CBrN/c2-1-3
• InChI key: ATDGTVJJHBUTRL-UHFFFAOYSA-N

Description

General description

Cyanogen bromide (CNBr) is a halogen halide. Its utility as a condensing agent during chemical ligation of oligodeoxyribonucleotides has been reported. Its threshold photoelectron (TPE) spectrum has been recorded under high resolution. The cryopolymerization of CNBr on irradiation has been investigated.

Application

Cyanogen bromide may be used:

• To activate polysaccharides for coupling with erythrocytes.
• As an oxidizing agent in the urine thaimine assay.
• In the preparation of 2-amino-5-(2′-thienyl)-1,3,4-oxadiazole.

Reaction with C₆₀Ph₅Cl produces a novel phenylated isoquinolino[3′,4′:1,2][60]fullerene.

Safety Information

• Pictograms: GHS06,GHS05,GHS09
• Signal Word: Danger
• Hazard Statements: H300 + H310 + H330,H314,H400
• Precautionary Statements: P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1B
• Supplementary Hazards: EUH032
• Storage Class Code: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flash Point(F): >149.0 °F - closed cup
• Flash Point(C): > 65 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves