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455652

Sigma-Aldrich

Sodium p-toluenesulfinate

95%

Synonym(s):

p-Toluenesulfinic acid sodium salt

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About This Item

Linear Formula:
4-CH3C6H4SO2Na
CAS Number:
Molecular Weight:
178.18
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

95%

impurities

<5% water

mp

>300 °C (lit.)

SMILES string

[Na+].Cc1ccc(cc1)S([O-])=O

InChI

1S/C7H8O2S.Na/c1-6-2-4-7(5-3-6)10(8)9;/h2-5H,1H3,(H,8,9);/q;+1/p-1

InChI key

KFZUDNZQQCWGKF-UHFFFAOYSA-M

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis of cyanohydrin trimethylsilyl ethers catalyzed by potassium p-toluenesulfinate.
Dekamin MG, et al.
Catalysis Communications, 9(6), 1352-1355 (2008)
Sodium p-toluenesulfinate/copper (II) acetate in free radical reactions of 5-aryl substituted alkenes.
Wang S-F, et al.
Tetrahedron, 55(8), 2273-2288 (1999)
Sodium p-Toluenesulfinate in Free Radical Reactions.
Chuang C-P.
Synthetic Communications, 23(17), 2371-2380 (1993)
Asymmetric induction in the palladium-catalyzed sulfonylation of allylic sulfinates and acetates with chiral phosphine ligands.
Hiroi K and Makino K.
Chemistry Letters (Jpn), 15(4), 617-620 (1986)
Efficient and Selective Trimerization of Aryl and Alkyl Isocyanates Catalyzed by Sodium p-Toluenesulfinate in the Presence of TBAI in a Solvent-Free Condition.
Moghaddam FM, et al.
Bulletin of the Chemical Society of Japan, 75(4), 851-852 (2002)

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