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243590

Sigma-Aldrich

Potassium perrhenate

99%

Synonym(s):

Potassium oxido(trioxo)rhenium, Potassium tetraoxorhenate(1-)

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About This Item

Linear Formula:
KReO4
CAS Number:
Molecular Weight:
289.30
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99%

form

powder

refractive index

n20/D 1.643 (lit.)

mp

550 °C (lit.)

density

4.887 g/mL at 25 °C (lit.)

SMILES string

[K+].[O-][Re](=O)(=O)=O

InChI

1S/K.4O.Re/q+1;;;;-1;

InChI key

QFKRWIFGDGKWLM-UHFFFAOYSA-N

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Application

The reduction of KReO4 in the preparation of cyclopentadienyltricarbonylrhenium complexes has potential as a model for the syntheses of technetium and rhenium organometallic radiopharmaceuticals.

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Spradau, T.W. Katzenellenbogen, J.A.
Organometallics, 17, 2009-2009 (1998)
Yuee Feng et al.
Inorganic chemistry, 48(23), 11058-11066 (2009-11-06)
The detailed syntheses of complexes of the form [Re(O)(X)(RNCH(2)CH(2))(2)N(Me)] (X = Me, Cl, I, R = mesityl, C(6)F(5)), 1-3, incorporating diamidoamine ancillary ligands are described. X-ray crystal structures for the complexes [Re(O)(Me)((C(6)F(5))NCH(2)CH(2))(2)N(Me)], 1a, [Re(O)(I)((C(6)F(5))N CH(2)CH(2))(2)N(Me)], 3a, and [Re(O)(I)((Mes)NCH(2))(2)N(Me)], 3b, are
Baikuntha P Aryal et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 17(1), 97-106 (2011-08-24)
Radiolabeled biomolecules are routinely used for clinical diagnostics. (99m)Tc is the most commonly used radioactive tracer in radiopharmaceuticals. (188)Re and (186)Re are also commonly used as radioactive tracers in medicine. However, currently available methods for radiolabeling are lengthy and involve
Julien Le Gal et al.
Journal of inorganic biochemistry, 105(6), 880-886 (2011-04-23)
Assembly of independent chemical modules through oxorhenium coordination by a NS(2)+S chelation motif was applied to the synthesis of RGD (Arg-Gly-Asp) analogs. Modules were assembled through oxorhenium chelation to give a series of 18 metal complexes in good yields and
Olesya A Nikonova et al.
Langmuir : the ACS journal of surfaces and colloids, 27(18), 11622-11628 (2011-08-13)
The use of an inorganic perrhenate ligand in the structure of early-transition-metal alkoxide precursors permits to achieve uniform self-assembly of the primary nanoparticles produced by their hydrolysis. The latter has been carried out in a hydrocarbon reaction medium by the

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