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901755

Sigma-Aldrich

nitro-Grela

≥95%

Synonym(s):

(1,3-Dimesitylimidazolidin-2-ylidene)dichloro(2-isopropoxy-5-nitrobenzylidene)ruthenium(II)

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About This Item

Empirical Formula (Hill Notation):
C31H37Cl2N3O3Ru
CAS Number:
502964-52-5
Molecular Weight:
671.62
UNSPSC Code:
12161600
NACRES:
NA.22

Assay

≥95%

form

powder

reaction suitability

core: ruthenium
reagent type: catalyst

mp

>300 °C

storage temp.

2-8°C

Related Categories

Application

nitro-Grela is a universal catalyst which provides good results in a wide spectrum of olefin metathesis transformations. The catalyst provides high efficiency in cross metathesis (CM) reactions between type 1 olefins and an electron deficient partner. The catalyst is very good for CM of disubstituted internal olefins.

Legal Information

Sold in collaboration with Apeiron Synthesis, Inc. Research quantities are 100 g / customer / year. For quantities that exceed the research limit, please contact the supplier at www.apeiron-synthesis.com.
PCT/EP2003/011222

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW1903
MKCV8695
MKCT0714
MKCR5902
MKCP2894

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Cross-metathesis reaction of vinyl sulfones and sulfoxides.
Grela K, et al.
Tetrahedron, 59, 4525-4531 (2003)
A highly efficient ruthenium catalyst for metathesis reactions.
Karol Grela et al.
Angewandte Chemie (International ed. in English), 41(21), 4038-4040 (2002-11-02)

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