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357634

Sigma-Aldrich

Nickel

wire, diam. 0.25 mm, ≥99.9%

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About This Item

Empirical Formula (Hill Notation):
Ni
CAS Number:
7440-02-0
Molecular Weight:
58.69
EC Number:
231-111-4
MDL number:
MFCD00011137
UNSPSC Code:
12161600
PubChem Substance ID:
24861929
NACRES:
NA.22

Quality Level

100

Assay

≥99.9%

form

wire

reaction suitability

core: nickel
reagent type: catalyst

resistivity

6.97 μΩ-cm, 20°C

diam.

0.25 mm

bp

2732 °C (lit.)

mp

1453 °C (lit.)

density

8.9 g/mL at 25 °C (lit.)

SMILES string

[Ni]

InChI

1S/Ni

InChI key

PXHVJJICTQNCMI-UHFFFAOYSA-N

Application

Nickel can be used as a catalyst in:
  • Various reactions such as hydrogenation, oxidative addition, C−H activation, oxidative cyclization, cross-coupling reaction.
  • Selective hydrogenolysis of the aromatic ethers.
  • Steam reforming process to produce hydrogen and synthesis gas.
  • Benzaldehyde hydrogenation.
  • Methanation of CO2.

Quantity

5 m (approximately 2.2 g)

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Danger

Hazard Statements

H317,H351,H372

Hazard Classifications

Carc. 2 - Skin Sens. 1 - STOT RE 1

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Benzaldehyde hydrogenation over supported nickel catalysts.
Saadi A, et al.
J. Mol. Catal. A: Chem., 253(1-2), 79-85 (2006)
Four challenges for nickel steam-reforming catalysts.
Sehested J
Catalysis Today, 111(1-2), 103-110 (2006)
Mesoporous nickel catalyst supported on multi-walled carbon nanotubes for carbon dioxide methanation.
Wang W, et al.
International Journal of Hydrogen Energy, 41(2), 967-975 (2016)
Alexey G Sergeev et al.
Science (New York, N.Y.), 332(6028), 439-443 (2011-04-23)
Selective hydrogenolysis of the aromatic carbon-oxygen (C-O) bonds in aryl ethers is an unsolved synthetic problem important for the generation of fuels and chemical feedstocks from biomass and for the liquefaction of coal. Currently, the hydrogenolysis of aromatic C-O bonds
Ornella Valenti et al.
Cerebral cortex (New York, N.Y. : 1991), 19(3), 658-674 (2008-07-18)
The prefrontal cortex receives multiple inputs from the hippocampal complex, which are thought to drive memory-guided behavior. Moreover, dysfunctions of both regions have been repeatedly associated with several psychiatric disorders. Therefore, understanding the interconnections and modulatory interactions between these regions
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