68630
(N-Methylphenylamino)triphenylphosphonium iodide
purum, ≥98.0% (NT)
Synonym(s):
Murahashi reagent, N-Methylanilinotriphenylphosphonium iodide
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About This Item
Empirical Formula (Hill Notation):
C25H23INP
CAS Number:
Molecular Weight:
495.34
Beilstein:
4075159
MDL number:
UNSPSC Code:
12352103
grade
purum
Assay
≥98.0% (NT)
mp
237-242 °C (dec.)
SMILES string
[I-].CN(c1ccccc1)[P+](c2ccccc2)(c3ccccc3)c4ccccc4
Other Notes
Reagent used for the activation of alcohols; reaction of the active intermediate with amines, thiols and azides to the respective derivatives; C-Alkylation or C-arylation of allylic alcohols
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Y. Tanigawa et al.
Journal of the American Chemical Society, 99, 2361-2361 (1977)
H.L. Goering et al.
The Journal of Organic Chemistry, 50, 1597-1597 (1985)
Tetrahedron Letters, 27, 6353-6353 (1986)
H.L. Goering et al.
The Journal of Organic Chemistry, 46, 2144-2144 (1981)
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