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909718

Sigma-Aldrich

2-(Isopropylsulfonyl)-1-phenylpropan-1-one

≥95%

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About This Item

Empirical Formula (Hill Notation):
C12H16O3S
CAS Number:
1343885-96-0
Molecular Weight:
240.32
MDL number:
MFCD20377596
UNSPSC Code:
12352005

Assay

≥95%

form

powder

reaction suitability

reaction type: C-C Bond Formation

mp

56-59 °C

storage temp.

−20°C

Application

2-(Isopropylsulfonyl)-1-phenylpropan-1-one is part of a suite of reagents developed by the Li group for late-stage functionalization of pharmaceutically relevant compounds. The reagents serve as precursors to alkyl radicals generated under light mediated, redox-neutral and catalyst free conditions for use in the Minisci alkylation of aromatics.

Other Notes

Catalyst-Free and Redox-Neutral Innate Trifluoromethylation and Alkylation of Aromatics Enabled by Light

related product

Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Certificates of Analysis (COA)

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Peng Liu et al.
Journal of the American Chemical Society, 139(40), 14315-14321 (2017-10-03)
The Minisci alkylation is useful to functionalize aromatics via alkyl radical addition. Current approaches to prepare alkyl radicals follow either oxidative or reductive pathways from various functional groups. Developing new strategy beyond these traditional methods remains elusive yet highly significant.

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