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795631

Sigma-Aldrich

Mesitylene pentamethylcyclopentadienyl ruthenium dimer

Synonym(s):

[RuCp*(mes)]2

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About This Item

Empirical Formula (Hill Notation):
C38H54Ru2
Molecular Weight:
712.98
UNSPSC Code:
12352103
PubChem Substance ID:
329768498
Pricing and availability is not currently available.

form

solid

Quality Level

100

storage temp.

−20°C

SMILES string

C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C.C[C]3C(C4[C](C)[C][C](C)[C][C]4C)[C](C)[C][C](C)[C]3.[Ru].[Ru]

InChI

1S/C18H24.2C10H15.2Ru/c1-11-7-13(3)17(14(4)8-11)18-15(5)9-12(2)10-16(18)6;2*1-6-7(2)9(4)10(5)8(6)3;;/h7-10,17-18H,1-6H3;2*1-5H3;;

InChI key

MIUITKYUOGVLMU-UHFFFAOYSA-N

Application

Used as an air-stable n-dopant for organic electronic devices.

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Passivation of trap states in unpurified and purified C60 and the influence on organic field-effect transistor performance
Olthof, S.;
Applied Physics Letters, 101, 253303-253303 (2012)
Selina Olthof et al.
Physical review letters, 109(17), 176601-176601 (2012-12-12)
Tail states in organic semiconductors have a significant influence on device performances by acting as traps in charge transport. We present a study of the controlled passivation of acceptor tail states in fullerene C(60) by the addition of electrons introduced
Song Guo et al.
Advanced materials (Deerfield Beach, Fla.), 24(5), 699-703 (2011-11-08)
Air-stable dimers of sandwich compounds including rhodocene and (pentamethylcyclopentadienyl)(arene)ruthenium and iron derivatives can be used for n-doping electron-transport materials with electron affinities as small as 2.8 eV. A p-i-n homojunction diode based on copper phthalocyanine and using rhodocene dimer as
n-Doping of Organic Electronic Materials Using Air-Stable Organometallics: A Mechanistic Study of Reduction by Dimeric Sandwich Compounds
Guo, S.;
Chemistry (Weinheim An Der Bergstrasse, Germany), 18, 14760-14760 (2012)

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