715131

Dichlorodi-μ-chlorobis[(1,2,3,6,7,8-η-2,7-dimethyl-2,6-octadiene-1,8-diyl]diruthenium(IV)

97%

• Synonym(s): Tetrachlorobis(2,7-dimethyl-2,6-octadienylene)diruthenium
• Empirical Formula (Hill Notation): C₂₀H₃₂Cl₄Ru₂
• CAS Number: 34801-97-3
• Molecular Weight: 616.42
• UNSPSC Code: 12161600
• PubChem Substance ID: 329762946
• NACRES: NA.22

Properties

• Assay: 97%
• form: powder
• reaction suitability: core: ruthenium; reagent type: catalyst
• mp: 193-202 °C (dec.)
• SMILES string: Cl[Ru]Cl.Cl[Ru]Cl.[CH2][C](C)[CH]CC[CH][C]([CH2])C.[CH2][C](C)[CH]CC[CH][C]([CH2])C
• InChI: 1S/2C10H16.4ClH.2Ru/c2*1-9(2)7-5-6-8-10(3)4;;;;;;/h2*7-8H,1,3,5-6H2,2,4H3;4*1H;;/q;;;;;;2*+2/p-4
• InChI key: UILPCDNRMPZVBB-UHFFFAOYSA-J

Description

Application

Catalyst for:

• Selective estragole to transanethole isomerization
• Regioselective alkylation of indoles with terminal alkynes
• Diyne polycyclotrimerization
• Deprotection of N-allylic amines
• Ring-opening metathesis polymerization of norbornene
• Polymerization of cycloalkenes and norbornene

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable