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About This Item
Linear Formula:
ClC6H3F2
CAS Number:
Molecular Weight:
148.54
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
98%
form
liquid
refractive index
n20/D 1.475 (lit.)
bp
127 °C (lit.)
density
1.353 g/mL at 25 °C (lit.)
SMILES string
Fc1ccc(Cl)c(F)c1
InChI
1S/C6H3ClF2/c7-5-2-1-4(8)3-6(5)9/h1-3H
InChI key
AJCSNHQKXUSMMY-UHFFFAOYSA-N
Application
1-Chloro-2,4-difluorobenzene was used in the preparation of series of benzonorbornadienes. It was also used in the preparation of difluoroarenes.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point(F)
91.4 °F - closed cup
Flash Point(C)
33 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Jason T Manka et al.
The Journal of organic chemistry, 69(6), 1967-1971 (2004-04-03)
Aryldiazo substituents were used in nucleophilic aromatic substitution reactions of halogens. The Ph-N=N- group activates ortho fluorine atoms toward alkylthiolation under mild conditions. In contrast, the Me(2)N-C(6)H(4)-N=N- group has virtually no activation effect in nucleophilic aromatic substitution, and serves as
K C Caster et al.
The Journal of organic chemistry, 66(9), 2932-2936 (2001-04-28)
This report details the synthesis of several benzonorbornadienes by Diels--Alder cycloaddition of cyclopentadiene derivatives with substituted benzyne intermediates, which were generated by low-temperature metal--halogen exchange of halobenzenes. General conditions were developed, allowing synthesis of most benzonorbornadienes described herein at the
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