276111

Diethyl nitromalonate

97%

• Linear Formula: O₂NCH(CO₂C₂H₅)₂
• CAS Number: 603-67-8
• Molecular Weight: 205.17
• EC Number: 210-052-8
• MDL number: MFCD00009142
• UNSPSC Code: 12352100
• PubChem Substance ID: 24856491
• NACRES: NA.22

Properties

• Assay: 97%
• form: liquid
• refractive index: n20/D 1.428 (lit.)
• bp: 78-80 °C/0.2 mmHg (lit.)
• density: 1.174 g/mL at 25 °C (lit.)
• SMILES string: CCOC(=O)C(C(=O)OCC)[N+]([O-])=O
• InChI: 1S/C7H11NO6/c1-3-13-6(9)5(8(11)12)7(10)14-4-2/h5H,3-4H2,1-2H3
• InChI key: DAKKWKYIQGMKOS-UHFFFAOYSA-N

Description

General description

Thermal decomposition of diethyl nitromalonate to furoxan has been studied[1].

Application

Diethyl nitromalonate has been used in the preparation of 5,5-diethoxycarbonyl-1-pyrroline N-oxide (DECPO)[2].

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 235.4 °F - closed cup
• Flash Point(C): 113 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves