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249556

Sigma-Aldrich

2-Fluoro-1-methylpyridinium p-toluenesulfonate

<5% 2-hydroxy-1-methylpyridinium p-toluenesulfonate, technical grade, ≥90%

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About This Item

Linear Formula:
C6H7FN · C7H7O3S
CAS Number:
58086-67-2
Molecular Weight:
283.32
Beilstein:
4345357
EC Number:
261-108-3
MDL number:
MFCD00011983
UNSPSC Code:
12352005
PubChem Substance ID:
24855003
NACRES:
NA.22

grade

technical grade

Assay

≥90%

form

solid

reaction suitability

reaction type: Coupling Reactions

impurities

<5% 2-hydroxy-1-methylpyridinium p-toluenesulfonate

mp

130-134 °C (lit.)

application(s)

peptide synthesis

SMILES string

C[n+]1ccccc1F.Cc2ccc(cc2)S([O-])(=O)=O

InChI

1S/C7H8O3S.C6H7FN/c1-6-2-4-7(5-3-6)11(8,9)10;1-8-5-3-2-4-6(8)7/h2-5H,1H3,(H,8,9,10);2-5H,1H3/q;+1/p-1

InChI key

HQWDKLAIDBOLFE-UHFFFAOYSA-M

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Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Tatsuya Higashi et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 825(2), 214-222 (2005-10-11)
A derivatization reagent, 2-hydrazino-1-methylpyridine, was developed for the liquid chromatography-electrospray ionization-mass spectrometry (LC-ESI-MS) of oxosteroids. The reagent quantitatively reacted with oxosteroids at 60 degrees C within 1h and the resulting derivatives of the mono-oxosteroids provided a 70-1600-fold higher sensitivity compared
D Narinesingh et al.
Analytical biochemistry, 194(1), 16-24 (1991-04-01)
Milk samples were analyzed for their lactose content using flow injection analysis and incorporating immobilized beta-galactosidase or beta-galactosidase/mutarotase and glucose oxidase/peroxidase bioreactors. These enzymes were immobilized, under mild conditions, on to a 2-fluoro-1-methylpyridinium salt-activated Fractogel support. The use of a
N R Shenoy et al.
Journal of protein chemistry, 12(2), 195-205 (1993-04-01)
In previous studies aimed at the sequencing of peptides and proteins from the carboxy terminus, we have derivatized the C-terminus to a thiohydantoin using acetic anhydride and trimethylsilylisothiocyanate (TMS-ITC) and subsequently hydrolyzed it to form a shortened peptide capable of
D Narinesingh et al.
Analytical biochemistry, 188(2), 325-329 (1990-08-01)
Serum samples were analyzed for their urea content using fluorescence flow injection analysis incorporating an immobilized urease bioreactor and a gas permeable separator. The urease was immobilized under mild and facile conditions to a hydrophilic 2-fluoro-1-methylpyridinium-activated support. The ammonia released
Ying-Hsuan Lin et al.
Rapid communications in mass spectrometry : RCM, 21(13), 1973-1983 (2007-05-26)
Even in trace amounts, estrogens such as 17beta-estradiol (E2), estrone (E1), estriol (E3), and 17alpha-ethinyl estradiol (EE2) may have adverse effects on humans and the aquatic ecosystem. Therefore, it is essential to be able to measure trace amounts of steroid
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