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164798

Sigma-Aldrich

Trifluoromethanesulfonyl chloride

≥99%

Synonym(s):

Triflyl chloride

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5 G
R 1 423,94
25 G
R 4 312,98

R 1 423,94

List PriceR 1 453,00

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5 G
R 1 423,94
25 G
R 4 312,98

About This Item

Linear Formula:
CF3SO2Cl
CAS Number:
Molecular Weight:
168.52
Beilstein:
1812106
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
form:
liquid
Assay:
≥99%

R 1 423,94

List PriceR 1 453,00

Please contact Customer Service for Availability

Request a Bulk Order

vapor pressure

10.36 psi ( 20 °C)

Quality Level

Assay

≥99%

form

liquid

refractive index

n20/D 1.334 (lit.)

bp

29-32 °C (lit.)

density

1.583 g/mL at 25 °C (lit.)

functional group

fluoro

storage temp.

2-8°C

SMILES string

FC(F)(F)S(Cl)(=O)=O

InChI

1S/CClF3O2S/c2-8(6,7)1(3,4)5

InChI key

GRGCWBWNLSTIEN-UHFFFAOYSA-N

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Application

Trifluoromethanesulfonyl chloride can be used as:
  • A trifluoromethylating agent for the fluoroalkylation of heterocycles, arenes, and heteroarenes.
  • A sulfonating agent for alcohols.
  • A chlorinating agent for carbanions.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Supplementary Hazards

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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Journal of the Chemical Society. Perkin Transactions 1, 627-627 (1991)
Marleen Häring et al.
The Journal of organic chemistry, 83(15), 7928-7938 (2018-05-29)
In this work, we demonstrate that useful C-C bond-forming photoredox catalysis can be performed in air using easily prepared gel networks as reaction media to give similar results as are obtained under inert atmosphere conditions. These reactions are completely inhibited
Journal of the Chemical Society. Perkin Transactions 1, 1339-1339 (1994)

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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