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145831

Sigma-Aldrich

Allylamine

98%

Synonym(s):

2-Propen-1-ylamine, 3-Amino-1-propene

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About This Item

Linear Formula:
CH2=CHCH2NH2
CAS Number:
107-11-9
Molecular Weight:
57.09
Beilstein:
635703
EC Number:
203-463-9
MDL number:
MFCD00008199
UNSPSC Code:
12352100
PubChem Substance ID:
24848749
NACRES:
NA.22

vapor density

2 (vs air)

vapor pressure

4.09 psi ( 20 °C)

Assay

98%

form

liquid

expl. lim.

22 %

refractive index

n20/D 1.420 (lit.)

bp

53 °C (lit.)

mp

−88 °C (lit.)

solubility

alcohol: miscible
chloroform: miscible
diethyl ether: miscible
water: miscible

density

0.761 g/mL at 25 °C (lit.)

SMILES string

NCC=C

InChI

1S/C3H7N/c1-2-3-4/h2H,1,3-4H2

InChI key

VVJKKWFAADXIJK-UHFFFAOYSA-N

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Application

Allylamine can be used:
  • To prepare a chemical gradient through plasma co-polymerization of octadiene and allylamine polymer on nanoporous alumina.
  • As a monomer to prepare plasma polymerized allylamine films in the study of their reactivity on Au and Si.
  • In a direct monocarboxymethylation reaction to yield N-formyl glycine derivatives.

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

-4.0 °F - closed cup

Flash Point(C)

-20 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Chemical reactivity of plasma polymerized allylamine (PPAA) thin films on Au and Si: Study of the thickness influence and aging of the films.
Moreau N, et al.
Surface and Coatings Technology, 205, S462-S465 (2011)
A mild and efficient method for the one-pot monocarboxymethylation of primary amines
Gibbs Timothy JK, et al.
Synlett, 2007(10), 1573-1576 (2007)
Versatile gradients of chemistry, bound ligands and nanoparticles on alumina nanopore arrays
Michelmore A, et al.
Nanotechnology, 22(41), 415601-415601 (2011)
A new approach to the immobilisation of poly (ethylene oxide) for the reduction of non-specific protein adsorption on conductive substrates.
Cole MA, et al.
Surface Science, 601(7), 1716-1725 (2007)
Sze Wing Tang et al.
ACS applied materials & interfaces, 11(21), 18988-18994 (2019-05-06)
Thermal scanning probe lithography (t-SPL) is a nanofabrication technique in which an immobilized thermolabile resist, such as polyphthalaldehyde (PPA), is locally vaporized by a heated atomic force microscope tip. Compared with other nanofabrication techniques, such as soft lithography and nanoimprinting
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