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243973

Sigma-Aldrich

Sodium bisulfite

ACS reagent

Synonym(s):

Sodium hydrogensulfite

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About This Item

Empirical Formula (Hill Notation):
NaHSO3
CAS Number:
7631-90-5
Molecular Weight:
104.06
UNSPSC Code:
12352302
PubChem Substance ID:
24854644
NACRES:
NA.21

grade

ACS reagent

Quality Level

200

form

powder or crystals

concentration

≥58.5% SO2

impurities

≤0.005% insolubles

pH

4.3 (10 g/L)

anion traces

chloride (Cl-): ≤0.02%

cation traces

Fe: ≤0.002%
heavy metals (as Pb): ≤0.001%

SMILES string

[Na+].OS([O-])=O

InChI

1S/Na.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+1;/p-2

InChI key

DWAQJAXMDSEUJJ-UHFFFAOYSA-L

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General description

Sodium bisulfite is a widely used industrial chemical as a reducing agent, catalyst, and preservative in pharmaceuticals and foods due to its antioxidative and antibacterial effects.
The aqueous solutions of sodium bisulfite are acidic in nature. Degradation of sodium bisulfite with acid forms sulfur dioxide gas.

Application

Sodium bisulfite (NaHSO3) has been used as a reagent to compose the immunoprecipitation (IP) buffer to chemically modify DNA and to synthesize arsenolipids (AsL).
It can also be used as a reagent during the synthesis of 5,6-dihydrouracil-6-sulfonate.
Sodium bisulfite can be used as:
  • A reagent to synthesize aldehyde-bisulfite adducts from aromatic and aliphatic aldehydes.
  • A catalyst in the solvent-free etherification of aromatic/aliphatic alcohols to synthesize symmetric and unsymmetric ethers via intermolecular dehydration.
  • An additive in the copper-catalyzed homocoupling of ketoxime carboxylates to synthesize symmetrical pyrroles.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302

Precautionary Statements

P264 - P270 - P301 + P312 - P501

Hazard Classifications

Acute Tox. 4 Oral

Supplementary Hazards

EUH031

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Journal of Korean medical science, 24(1), 97-103 (2009-03-10)
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European Journal of Lipid Science and Technology, 118(3), 445-452 (2015)
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Chemical & pharmaceutical bulletin, 61(1), 1-7 (2012-11-06)
The purpose of this study was to predict the stability of imipenem in a mixed infusion. The hydrolysis of imipenem in aqueous solution was found to be accelerated by pH, and by increasing concentrations of sodium bisulfite (SBS) and L-cysteine.
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