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About This Item
Empirical Formula (Hill Notation):
C5H5BrN2
CAS Number:
Molecular Weight:
173.01
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
form
solid
mp
63-67 °C
functional group
bromo
SMILES string
Nc1ncccc1Br
InChI
1S/C5H5BrN2/c6-4-2-1-3-8-5(4)7/h1-3H,(H2,7,8)
InChI key
RBCARPJOEUEZLS-UHFFFAOYSA-N
Related Categories
Application
2-Amino-3-bromopyridine may be used to synthesize:
- 2-acylamido-3-bromopyridines
- 2-anilino-3-bromopyridine
- 3-[(2-methoxyphenyl)ethynyl]pyridin-2-amine
- 3-[(4-methoxyphenyl)ethynyl]pyridin-2-amine
- N-(bromopyridyl)amidines
- carbolines via palladium catalyzed arylation followed by palladium catalyzed amination reaction
- 2-amino-3-cyanopyridine via palladium catalyzed cyanation reaction with potassium ferro-cyanide in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene [DBU]
- nitro-substituted N,N′-dipyridinylamines via palladium catalyzed coupling reaction with 2-chloro-3-nitropyridine in the presence of Xantphos ligand
- 2-amino-3-iodopyridine via reaction with sodium iodide in the presence of copper(I)iodide and trans-N,N′-dimethylcyclohexane-1,2-diamine
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis of pyridopyrimidines by palladium-catalyzed isocyanide insertion.
Este'vez V, et al.
ACS Catalysis, 4(1), 40-43 (2013)
"Smiles Rearrangement as a Tool for the Preparation of Dihydrodipyridopyrazines"
Patriciu I-O, et al.
Organic Letters, 11(23), 5502-5505 (2009)
Phosphonylation of 2-Amino-and 2-Amido-3-bromopyridines and 2-Amino-3-chloroquinoxalines with Triethyl Phosphite.
Adam M, et al.
European Journal of Organic Chemistry, 27, 4655-4665 (2009)
"Syntheses of pyrido [1, 2-a][1, 3, 5] triazin-4-one C-deoxyribonucleosides"
Oda H, et al.
Tetrahedron, 64(45), 11021-11029 (2007)
Novel synthetic strategy of carbolines via palladium-catalyzed amination and arylation reaction.
Iwaki T, et al.
Journal of the Chemical Society. Perkin Transactions 1, 11, 1505-1510 (1999)
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