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Sigma-Aldrich

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide

≥98.0% (T)

Synonym(s):

BMP-BTI

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About This Item

Empirical Formula (Hill Notation):
C11H20F6N2O4S2
CAS Number:
Molecular Weight:
422.41
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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description

electrochemical window -3.0 - +2.4 V

Assay

≥98.0% (T)

impurities

≤0.2% water

viscosity

548 stokes

mp

-18 °C

functional group

fluoro

SMILES string

CCCC[N+]1(C)CCCC1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C9H20N.C2F6NO4S2/c1-3-4-7-10(2)8-5-6-9-10;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h3-9H2,1-2H3;/q+1;-1

InChI key

HSLXOARVFIWOQF-UHFFFAOYSA-N

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General description

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide is a room temperature ionic liquid (RTIL) with a wide electrochemical window (5.5V) and high viscosity, making it a useful candidate in electrochemical energy applications.[1]

Application

BMP-BTI has been used as a derivatization media for dimethyl sulfate (DMS) with dibenzazepine.[2]

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Electrochemical study of copper chloride complexes in the RTIL 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide
Vainikka, Tuomas, et al.
Electrochimica Acta, 87, 739-748 (2013)
Physicochemical characterization of 1-butyl-3-methylimidazolium and 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide
Vranes, Milan, et al.
Journal of Chemical and Engineering Data, 57.4, 1072-1077 (2012)
Aluminium Speciation in 1?Butyl?1?Methylpyrrolidinium Bis (trifluoromethylsulfonyl) amide/AlCl3 Mixtures
Rocher, Nathalie M., et al.
Chemistry?A European Journal , 15.14, 3435-3447 (2009)
Novel amperometric sensors for nitrite detection using electrodes modified with PEDOT prepared in ionic liquids
Gligor, Delia, et al.
Journal of Solid State Electrochemistry, 21.1, 281-290 (2017)
Electrochemical behavior of oxygen/superoxide ion couple in 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide room-temperature molten salt
Katayama, Yasushi, et al.
Journal of the Electrochemical Society, 152.8, E247-E250 (2005)

Articles

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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