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Sigma-Aldrich

Tin(II) acetate

Synonym(s):

Stannous acetate, Tin acetate, Tin diacetate

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About This Item

Linear Formula:
Sn(CH3CO2)2
CAS Number:
Molecular Weight:
236.80
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

form

solid

reaction suitability

core: tin
reagent type: catalyst

mp

180-182 °C (lit.)

SMILES string

CC(=O)O[SnH2]OC(C)=O

InChI

1S/2C2H4O2.Sn/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

PNOXNTGLSKTMQO-UHFFFAOYSA-L

General description

Tin(II) acetate can be used as a photocatalyst to produce Arylstannane(IV) Reagents.

Application

  • Enhances the rate of thermal depolymerization of poly(lactic acid) fibers
  • Reactant for the synthesis of Sn-Cu bimetallic nanoparticles
  • used in in preparation of tin anode by organic electroplating for rechargeable thin-film batteries
  • Used as tin source for preparation of high surface area tin oxide catalysts
Used to prepare tin(IV) oxide thin films by photochemical vapor deposition. With palladium(II) acetate, an efficient catalytic system for C-H activation of the methoxy group of anisole.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Junshan Li et al.
ChemSusChem, 12(7), 1451-1458 (2019-01-25)
Co-Sn solid-solution nanoparticles with Sn crystal structure and tuned metal ratios were synthesized by a facile one pot solution-based procedure involving the initial reduction of a Sn precursor followed by incorporation of Co within the Sn lattice. These nanoparticles were
Keiko Yakabi et al.
ChemSusChem, 10(18), 3652-3659 (2017-08-15)
The Baeyer-Villiger oxidation is a key transformation for sustainable chemical synthesis, especially when H
Photocatalytic Reaction of Aryl Halides with Tin (II) Acetate to Generate Arylstannane (IV) Reagents
Zemtsov AA, et al.
ACS Catalysis, 13, 12766-12773 (2023)
The Journal of Organic Chemistry, 59, 7521-7521 (1994)
Gianvito Caputo et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 18(12), 1635-1641 (2017-04-04)
The localized in situ formation of tin dioxide (SnO

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