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283738

Sigma-Aldrich

Potassium aquapentachlororuthenate(III)

Synonym(s):

Dipotassium aquapentachlororuthenate(III)

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About This Item

Linear Formula:
K2RuCl5(H2O)
CAS Number:
14404-33-2
Molecular Weight:
374.55
EC Number:
238-374-4
MDL number:
MFCD00011524
UNSPSC Code:
12352302
PubChem Substance ID:
24857128
NACRES:
NA.23

form

powder

Quality Level

200

concentration

26-30% Ru (gravimetric)

technique(s)

H-NMR: suitable

SMILES string

O.[K+].[K+].Cl[Ru--](Cl)(Cl)(Cl)Cl

InChI

1S/5ClH.2K.H2O.Ru/h5*1H;;;1H2;/q;;;;;2*+1;;+3/p-5

InChI key

SRVGBBZEPHUDFZ-UHFFFAOYSA-I

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Application

The product may be used for eletrodeposition of bifunctional catalyst films, PtRu on nanoporous TiO2 substrates.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL1248
BCCJ7941
BCCF4645
BCCC2633
BCBS1401V

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Nanoporous TiO 2-supported bimetallic catalysts for methanol oxidation in acidic media.
Hepel M, et al.
Electrochemical Communications, 8(9), 1439-1444 (2006)
Sunder N Dhuri et al.
Dalton transactions (Cambridge, England : 2003), 44(16), 7634-7642 (2015-03-27)
A mononuclear high-valent trans-dioxoruthenium(VI) complex, trans-[Ru(VI)(TMC)(O)2](2+) (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), was synthesized and characterized by various spectroscopic techniques and X-ray crystallography. The reactivity of the trans-[Ru(VI)(TMC)(O)2](2+) complex was investigated in hydride transfer and hydrogen atom transfer reactions. The mechanism of hydride

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