1.01845

tert-Butyl methyl ether

for liquid chromatography LiChrosolv^®

• Synonyme(s) : tert-Butyl methyl ether, MTBE, MTB, 2-Methoxy-2-methylpropane, Methyl tert-butyl ether, TBME
• Formule linéaire : (CH₃)₃COCH₃
• Numéro CAS: 1634-04-4
• Poids moléculaire : 88.15
• Numéro MDL: MFCD00008812
• Code UNSPSC : 12191502
• Numéro de classement CE : 216-653-1
• Nomenclature NACRES : NA.03
• Essai: ≥99.8% (GC)
• Technique(s): HPLC: suitable
• pb: 55.3 °C/1013 hPa
• Pression de vapeur: 268 hPa ( 20 °C)

Propriétés

• Pression de vapeur: 268 hPa ( 20 °C)
• Niveau de qualité: 100
• Description: isocratic
• Gamme de produits: LiChrosolv^®
• Essai: ≥99.8% (GC)
• Forme: liquid
• Température d'inflammation spontanée: 460 °C
• Puissance: >2000 mg/kg LD₅₀, oral (Rat); >2000 mg/kg LD₅₀, skin (Rabbit)
• Limite d'explosivité: 1.5-8.5 % (v/v)
• Technique(s): HPLC: suitable
• Impuretés: ≤0.0002 meq/g Acidity; ≤0.0002 meq/g Alkalinity; ≤0.02% Water
• Résidus d'évap.: ≤2.0 mg/L
• Transmittance: 240 nm, ≥60%; 255 nm, ≥85%; 280 nm, ≥98%
• Viscosité cinématique: 0.409 cSt(40 °C)
• pb: 55.3 °C/1013 hPa
• Pf: -108.6 °C
• Température de transition: flash point -28 °C
• Solubilité: 42 g/L
• Densité: 0.74 g/cm³ at 20 °C
• Température de stockage: 2-30°C
• Chaîne SMILES: O(C(C)(C)C)C
• InChI: 1S/C5H12O/c1-5(2,3)6-4/h1-4H3
• Clé InChI: BZLVMXJERCGZMT-UHFFFAOYSA-N

Description

Description générale

LiChrosolv^® solvents provide high degree of UV transmittance, low particle count, low acidity and alkalinity and low evaporation residue level. This makes them ideal for reproducible separations.

Application

Intended for HPLC and UHPLC-MS applications.

Used as an extraction solvent to analyze nucleotides of Drosophila gut microbiome in flies prior to LC-MS analysis.[1]

Caractéristiques et avantages

• suitability tested and specified for UHPLC-MS and UHPLC-UV: for analytical flexibility
• specified quality in positive and negative in positive and negative electrospray ionization (ESI) and atmospheric-pressure chemical ionization-mass spectrometry (APCI-MS) for lowest detection limits and confidence in analyses for all important MS modes (test 1)

—ESI/APCI (+) < 2 ppb
—ESI/APCI (-) < 10 ppb

• lowest impurity profile: for interference-free baselines (test 2)
• Microfiltered through 0.2 μm filter (test 3) to provide

—a long lifespan to filters and mechanical parts of HPLC systems
—reduced risk of column clogging

• packed in borosilicate glass bottles for minimized metal ion contaminations
• lowest levels of trace metal impurities for a minimum metal ion adduct formation

—<5 ppb

• lowest level of polyethylene glycol (PEG) impurities in UHPLC-MS solvent lineup (PEG S/N signal-to-noise-ratio < 50)

Notes préparatoires

Product filtered through a 0.2 μm filter

Remarque sur l'analyse

Purity (GC): ≥ 99.8 %
Identity (IR): conforms
Evaporation residue: ≤ 2.0 mg/l
Water: ≤ 0.02 %
Acidity: ≤ 0.0002 meq/g
Alkalinity: ≤ 0.0002 meq/g
Transmission (at 240 nm): ≥ 60 %
Transmission (at 255 nm): ≥ 85 %
Transmission (from 280 nm): ≥ 98 %
Filtered by 0.2 µm filter

Autres remarques

Explore various lab safety accessories and equipment for safe handling of solvents to increase your safety level from the first usage.

Informations légales

LICHROSOLV is a registered trademark of Merck KGaA, Darmstadt, Germany

Informations sur la sécurité

• Pictogrammes: GHS02,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H225 - H315
• Conseils de prudence: P210 - P233 - P240 - P241 - P242 - P303 + P361 + P353
• Classification des risques: Flam. Liq. 2 - Skin Irrit. 2
• Code de la classe de stockage: 3 - Flammable liquids
• Classe de danger pour l'eau (WGK): WGK 1
• Point d'éclair (°F): -18.4 °F - closed cup
• Point d'éclair (°C): -28 °C - closed cup