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771082

Sigma-Aldrich

Hoveyda-Grubbs Catalyst® M2001

Umicore

Synonyme(s) :

Grubbs Catalyst® Z-Selective, Hoveyda-Grubbs Catalyst® MZ1c (C633), Grubbs Catalyst® C633, Grubbs Z-Selective Metathesis Catalyst, Grubbs′ Z-Selective Catalyst, [2-(1-Methylethoxy-O)phenylmethyl-C](nitrato-O,O′){rel-(2R,5R,7R)-adamantane-2,1-diyl[3-(2,4,6-trimethylphenyl)-1-imidazolidinyl-2-y lidene]}ruthenium, [2-(1-Methylethoxy-O)phenylmethyl-C](nitrato-O,O′){rel-(2R,5R,7S)-tricyclo[3.3.1.13,7]decane-2,1-diyl[3-(2,4,6-trimethylphenyl)-1-imidazolidinyl-2-ylidene]}ruthenium

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About This Item

Formule empirique (notation de Hill):
C32H41N3O4Ru
Numéro CAS:
1352916-84-7
Poids moléculaire :
632.76
Code UNSPSC :
12161600
Nomenclature NACRES :
NA.22

Niveau de qualité

100

Forme

solid

Pertinence de la réaction

core: ruthenium
reagent type: catalyst
reaction type: Olefin Metathesis

Pf

200-215 °C

Température de stockage

2-8°C

Catégories apparentées

Application

Olefin Metathesis Catalyst for cis-selective ring-opening metathesis polymerization and Z-Selective Olefin Metathesis.

Autres remarques

Grubbs Catalyst® Technology for Olefin Metathesis by Aldrich

Informations légales

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Certificats d'analyse (COA)

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Benjamin K Keitz et al.
Journal of the American Chemical Society, 134(4), 2040-2043 (2012-01-14)
Cis-selective ring-opening metathesis polymerization of several monocyclic alkenes as well as norbornene and oxanorbornene-type monomers using a C-H activated, ruthenium-based metathesis catalyst is reported. The cis content of the isolated polymers depended heavily on the monomer structure and temperature. A
Benjamin K Keitz et al.
Journal of the American Chemical Society, 134(1), 693-699 (2011-11-22)
Several new C-H-activated ruthenium catalysts for Z-selective olefin metathesis have been synthesized. Both the carboxylate ligand and the aryl group of the N-heterocyclic carbene have been altered and the resulting catalysts evaluated using a range of metathesis reactions. Substitution of

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