675067

12-Mercaptododecanoic acid

96%

• Synonyme(s) : MDA
• Formule empirique (notation de Hill): C₁₂H₂₄O₂S
• Numéro CAS: 82001-53-4
• Poids moléculaire : 232.38
• Numéro MDL: MFCD08705252
• Code UNSPSC : 12352103
• ID de substance PubChem : 24885255
• Nomenclature NACRES : NA.23

Propriétés

• Niveau de qualité: 100
• Pureté: 96%
• Forme: solid
• Pf: 45-50 °C
• Température de stockage: 2-8°C
• Chaîne SMILES: OC(=O)CCCCCCCCCCCS
• InChI: 1S/C12H24O2S/c13-12(14)10-8-6-4-2-1-3-5-7-9-11-15/h15H,1-11H2,(H,13,14)
• Clé InChI: SDAWVOFJSUUKMR-UHFFFAOYSA-N

Description

Description générale

12-Mercaptododecanoic acid (MDA) is a carboxylic acid terminated thiol that forms self-assembled monolayers (SAMs) on a variety of surfaces. It provides a blocking effect and immobilizes the surface atoms.

Application

MDA can functionalize gold nanoparticles which can form screen printed electrodes for electrochemical detection. It can also form ligands with cadmium selenium (CdSe) quantum dots (ODs) which can be deposited on titanium oxide(TiO₂) based films.

This compound is used to produce hydrophilic SAMs. The resulting monolayers which are terminated with carboxylic acids can be further functionalized to introduce more complex end groups. Used in a study of the effect of molecular structure on the precision of copper-bound α,ω-mercaptoalkanoic acid "molecular ruler" stacks.

Informations sur la sécurité

• Pictogrammes: GHS07
• Mention d'avertissement: Warning
• Mentions de danger: H315,H319,H335
• Conseils de prudence: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classification des risques: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): >230.0 °F
• Point d'éclair (°C): > 110 °C
• Équipement de protection individuelle: dust mask type N95 (US), Eyeshields, Gloves