N32407
Bicyclo[2.2.1]hept-2-ene
99%
Synonym(s):
2-Norbornene, Norbornylene
Sign Into View Organizational & Contract Pricing
All Photos(3)
About This Item
Empirical Formula (Hill Notation):
C7H10
CAS Number:
Molecular Weight:
94.15
Beilstein:
1098544
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
![Bicyclo[2.2.1]hepta-2,5-diene 98%](/deepweb/assets/sigmaaldrich/product/structures/304/819/dfa7c176-c370-4fb5-acf1-28d751241a50/640/dfa7c176-c370-4fb5-acf1-28d751241a50.png)
Quality Level
Assay
99%
form
solid
bp
96 °C (lit.)
mp
44-46 °C (lit.)
SMILES string
C1C[C@H]2C[C@@H]1C=C2
InChI
1S/C7H10/c1-2-7-4-3-6(1)5-7/h1-2,6-7H,3-5H2/t6-,7+
InChI key
JFNLZVQOOSMTJK-KNVOCYPGSA-N
Looking for similar products? Visit Product Comparison Guide
General description
Bicyclo[2.2.1]hept-2-ene is a cyclic olefin used in the transition metal-catalyzed dimerization of alkene.
The vinylic polymerization of bicyclo[2.2.1]hept-2-ene (norbornene) with Co(II) compounds and the metallocene [η5-(C5Me5)Co-η2-Cl]2, in chlorobenzene activated with methylaluminoxane (MAO) has been reported. Co(II) catalyzed polymerization of bicyclo[2.2.1]hept-2-ene in the presence of ethene has been reported.
The vinylic polymerization of bicyclo[2.2.1]hept-2-ene (norbornene) with Co(II) compounds and the metallocene [η5-(C5Me5)Co-η2-Cl]2, in chlorobenzene activated with methylaluminoxane (MAO) has been reported. Co(II) catalyzed polymerization of bicyclo[2.2.1]hept-2-ene in the presence of ethene has been reported.
Application
Bicyclo[2.2.1]hept-2-ene may be used in the preparation of cis,exo-2,3-diarylsubstituted bicyclo[2.2.1]heptanes or bicyclo [2.2.1] hept-2-enes.
related product
Product No.
Description
Pricing
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Sol. 1 - Repr. 2
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
WGK 1
Flash Point(F)
17.6 °F - closed cup
Flash Point(C)
-8 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Co (II)-catalyzed polymerization of bicyclo [2.2. 1] hept-2-ene in the presence of ethene.
Alt FP and Heitz W.
Acta Polym., 49(9), 477-481 (1998)
The Non-planarity of the Bicyclo [2.2. 1] hept-2-ene Double bond. Crystal Structures of Bicyclo [2.2. 2] oct-2-ene, Bicyclo [2.2. 1] hept-2-ene, and Bicyclo [2.1. 1] hex-2-ene Systems
Pinkerton, et al.
Helvetica Chimica Acta, 67, 1136-1153 (1984)
A new palladium catalyzed synthesis of cis, exo-2, 3-diarylsubstituted bicyclo [2.2. 1] heptanes or bicyclo [2.2. 1] hept-2-enes.
Catellani M, et al.
Tetrahedron, 45(16), 5263-5268 (1989)
A novel catalytic route to 2-bicyclo [2.2. 1] hept-2-ylidenebicyclo [2.2. 1]-heptane involving CH bond activation of bicyclo [2.2. 1] hept-2-ene
Malinowska, et al.
Journal of Molecular Catalysis. B, Enzymatic, 226, 259-262 (2005)
Srivari Chandrasekhar et al.
Chemical communications (Cambridge, England), (14)(14), 1548-1550 (2006-04-01)
The oligomers of constrained cis-exo-beta-norbornene amino acid were synthesised and characterised by extensive NMR, CD, IR and MD studies. The results showed the formation of both right and left handed consecutive 6-membered hydrogen-bonded strands for [2S,3R] and [2R,3S] enantiomers, respectively.
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service