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381071

Sigma-Aldrich

2-Aminoterephthalic acid

99%

Synonym(s):

2-Aminobenzene-1,4-dicarboxylic acid

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About This Item

Linear Formula:
H2NC6H3-1,4-(CO2H)2
CAS Number:
10312-55-7
Molecular Weight:
181.15
Beilstein:
2805625
MDL number:
MFCD00134536
UNSPSC Code:
12352106
PubChem Substance ID:
24863787
NACRES:
NA.22

Quality Level

100

Assay

99%

form

powder, crystals or chunks

reaction suitability

reaction type: solution phase peptide synthesis

mp

324 °C (dec.) (lit.)

application(s)

peptide synthesis

SMILES string

Nc1cc(ccc1C(O)=O)C(O)=O

InChI

1S/C8H7NO4/c9-6-3-4(7(10)11)1-2-5(6)8(12)13/h1-3H,9H2,(H,10,11)(H,12,13)

InChI key

GPNNOCMCNFXRAO-UHFFFAOYSA-N

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Application

2-Aminoterephthalic acid can be used to synthesize:
  • Lanthanide coordination polymers with 1,10-phenanthroline by hydrothermal method.
  • Blue-emitting derivatives of 2-aminoterephthalic acid.
  • Amino-functionalized Zr-terephthalate (UiO-66), an excellent catalyst for selective synthesis of jasminaldehyde.
  • IRMOF-3, a zinc aminoterephthalate metal-organic framework useful as a catalyst for the Knoevenagel condensation of benzaldehyde and ethyl cyanoacetate.
  • Polymeric composite membrane with excellent CO2 separation capabilities.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
WXBF2540V
WXBF3291V
WXBF4605V
MKCW0686
MKCT8731

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Weiwei Zhao et al.
PloS one, 12(6), e0178513-e0178513 (2017-06-06)
UiO-66 analogues are good candidates as stationary phase in HPLC because of their chemical/thermal stability, large surface area, and two cage structures. Here, two UiO-66 analogues, UiO-66-NH2 and UiO-67, were synthesized and used as stationary phase in HPLC to evaluate
An amino-modified Zr-terephthalate metal?organic framework as an acid?base catalyst for cross-aldol condensation
Vermoortele F, et al.
Chemical Communications (Cambridge, England), 47(5), 1521-1523 (2011)
Hao Zhang et al.
Nanomaterials (Basel, Switzerland), 10(9) (2020-09-17)
A combination of calcination and hydrothermal processing was used to prepare a g-C3N4/UiO-66-NH2/CdS photocatalyst, and the degradation of tetracycline (TC) over this material was assessed. The photocatalytic performance of this nanocomposite was approximately 4.4 and 2.3 times those of CdS
Kristian Blindheim Lausund et al.
Dalton transactions (Cambridge, England : 2003), 46(48), 16983-16992 (2017-11-28)
Thin films of metal-organic frameworks (MOFs) prepared using all-gas-phase techniques such as atomic/molecular layer deposition (ALD/MLD) are emerging due to their potential for enabling suitable applications. Their high and specific porosity enables their use as membranes for separations and as
Yuqian Jia et al.
Journal of chromatography. A, 1551, 21-28 (2018-04-14)
A core-shell discoid shaped indium (III) sulfide@metal-organic framework (MIL-125(Ti)) nanocomposite was synthesized by a solvothermal method and explored as an adsorbent material for dispersive solid-phase extraction (d-SPE). The as-synthesized sorbent was characterized by scanning electron microscopy, energy-dispersive spectroscopy, transmission electron
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