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17455

Sigma-Aldrich

tert-Butyl α-bromoisobutyrate

≥98.0%

Synonym(s):

tert-Butyl 2-bromo-2-methylpropionate

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About This Item

Linear Formula:
(CH3)2CBrCOOC(CH3)3
CAS Number:
23877-12-5
Molecular Weight:
223.11
Beilstein:
1905654
EC Number:
245-924-7
MDL number:
MFCD00051908
UNSPSC Code:
12352100
PubChem Substance ID:
57647651
NACRES:
NA.22

Quality Level

100

Assay

≥98.0%

refractive index

n20/D 1.436

density

1.196 g/mL at 20 °C (lit.)

functional group

bromo
ester

SMILES string

CC(C)(C)OC(=O)C(C)(C)Br

InChI

1S/C8H15BrO2/c1-7(2,3)11-6(10)8(4,5)9/h1-5H3

InChI key

IGVNJALYNQVQIT-UHFFFAOYSA-N

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Application

tert-Butyl α-bromoisobutyrate was used as an initiator in the atom transfer radical polymerisation (ATRP) of 2-(acetoacetoxy)ethyl methacrylate (AEMA).

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H319,H335

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCBQ0503V
1317159V
1317159
338552/1
1143074

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Theodora Krasia et al.
Chemical communications (Cambridge, England), (4)(4), 538-539 (2003-03-18)
Reversible addition-fragmentation chain transfer (RAFT) radical polymerisation enables to synthesise well-defined homopolymers and block copolymers based on 2-(acetoacetoxy)ethyl methacrylate, which are capable to strongly coordinate to metals and metal ions.
Shin-Nosuke Nishimura et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(60), 15050-15058 (2017-08-11)
Precisely incorporating a wide range of structural and functional multiblocks along a polymer backbone is a significant challenge in polymer chemistry and offers promising opportunities to design highly ordered materials, including controlled polymer folding. Herein, a facile and versatile strategy

Protocols

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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