169021
Phenyl disulfide
99%
Synonym(s):
Diphenyl disulfide, NSC 2689
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About This Item
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Quality Level
Assay
99%
form
powder
mp
58-60 °C (lit.)
solubility
xylene: soluble 3%, clear, colorless to yellow
functional group
disulfide
SMILES string
S(Sc1ccccc1)c2ccccc2
InChI
1S/C12H10S2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H
InChI key
GUUVPOWQJOLRAS-UHFFFAOYSA-N
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General description
Phenyl disulfide is used as a precursor for the synthesis of phenyl selenosulfide (PhS-SePh), which is vital in Li-ion battery production.
Application
Phenyl disulfide is the hydrolysis product of dyfonate( insecticide). Phenyl disulfide (diphenyl disulphide) participates in hydrothiolation of alkynes via amine-mediated single electron transfer mechanism.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Mixture is better: enhanced electrochemical performance of phenyl selenosulfide in rechargeable lithium batteries
Journal of the Chemical Society. Chemical Communications, 54, 8873-8876 (2018)
Identification of hydrolytic metabolites of dyfonate in alkaline aqueous solutions by using high performance liquid chromatography-UV detection and gas chromatography-mass spectrometry.
International Journal of Environmental Analytical Chemistry, 90(12), 948-961 (2010)
Toxicology, 191(2-3), 169-178 (2003-09-11)
Organochalcogens are important intermediates and useful reagents in organic synthesis, which can increase human exposure risk to these chemicals in the workplace. As well, there are a number of reported cases of acute toxicity following organochalcogen ingestion of vitamins and
Mutation research, 385(1), 41-46 (1997-12-31)
S-Methyl methanethiosulfonate (MMTS) and diphenyl disulfide (DPDS) are temporary enzyme-sulfhydryl blocking agents. They are naturally occurring phytoalexin-like and synthetic substances known to be very potent bio-antimutagens in Escherichia coli B/r WP2. In the present paper, the suppressing effects of MMTS
Organic letters, 11(15), 3298-3301 (2009-09-02)
Hydrothiolation of alkynes proceeds with diphenyl disulfide and tripropylamine. Amine-mediated single electron transfer to diphenyl disulfide can be proposed for the reaction mechanism. Applications of the method to radical cyclizations of eneyne compounds are also presented.
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