I0514
Diethyl isocyanomethylphosphonate
>97% (GC)
Synonym(s):
Isocyanomethylphosphonic acid diethyl ester
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About This Item
Linear Formula:
CNCH2P(O)(OC2H5)2
CAS Number:
Molecular Weight:
177.14
Beilstein:
4674920
MDL number:
UNSPSC Code:
12352000
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Assay
>97% (GC)
refractive index
n20/D 1.433 (lit.)
bp
84-87 °C/0.1 mmHg (lit.)
density
1.105 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CCOP(=O)(C[N+]#[C-])OCC
InChI
1S/C6H12NO3P/c1-4-9-11(8,6-7-3)10-5-2/h4-6H2,1-2H3
InChI key
ICURVXBGGDVHDT-UHFFFAOYSA-N
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Application
Reactant for:
- Copper-catalyzed cycloaddition reactions
- Preparation of orally bioavailable diamide prodrugs that lower glucose in diabetic animals through inhibition of fructose-1,6-bisphosphatase
- Synthesis of sterol analogs as antifungal agents against plant pathogens
- Asymmetric synthesis of steroidal 2,5-diketopiperazines prepared via isocyanide chemistry based on stereoselective Ugi four component condensation and subsequent cyclocondensation reactions
- The Passerini reaction
Precursor for synthesis of phosphonic acid analogs of α-amino acids.
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Find documentation for the products that you have recently purchased in the Document Library.
Schollkopf, U. and Wintel, T.
Synthesis, 1033-1033 (1984)
Rachon, J.
Synthesis, 219-219 (1984)
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