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31250

Sigma-Aldrich

Potassium chromate

puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99.5%

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About This Item

Linear Formula:
K2CrO4
CAS Number:
7789-00-6
Molecular Weight:
194.19
EC Number:
232-140-5
MDL number:
MFCD00011368
UNSPSC Code:
41116107
PubChem Substance ID:
329753699

grade

ACS reagent
puriss. p.a.

Agency

reag. Ph. Eur.

vapor density

6.7 (vs air)

Assay

≥99.5%

impurities

≤0.005% in water insoluble matters

pH

8.6-9.8 (20 °C, 5%)

mp

971 °C (lit.)

anion traces

chloride (Cl-): ≤10 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg
Fe: ≤20 mg/kg
Na: ≤200 mg/kg
Pb: ≤50 mg/kg

SMILES string

[K+].[K+].[O-][Cr]([O-])(=O)=O

InChI

1S/Cr.2K.4O/q;2*+1;;;2*-1

InChI key

XMXNVYPJWBTAHN-UHFFFAOYSA-N

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General description

Potassium chromate (K2CrO4) is the potassium salt having morphological features similar to potassium sulfate (isostructural). Its crystals exhibit rhombic crystal system. It can be manufactured by reacting potassium dichromate with potassium hydroxide. It has been reported to crystallize in orthorhombic space group. Production of potassium chromat by a new reaction system of KOH-KNO3-H2O (binary submolten salt system) has been proposed.

Signal Word

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Irrit. 2 - Muta. 1B - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Redetermination of the structures of potassium sulphate and potassium chromate: the effect of electrostatic crystal forces upon observed bond lengths.
McGinnety JA.
Acta Crystallographica Section B, Structural Science, 28(9), 2845-2852 (1972)
Comparative Study of Factors Influencing the Action of Corrosion Inhmitors for Mild Steel in Neutral Solution: II. Potassium Chromate.
Mercer AD and Jenkins IR.
British Corrosion Journal, 3(3), 130-135 (1968)
Eagleson M.
Concise Encyclopedia Chemistry, 881-881 (1994)
A new method of potassium chromate production from chromite and KOH-KNO3-H2O binary submolten salt system.
Sun Z, et al.
AIChE Journal, 55(10), 2646-2656 (2009)
Ying Li et al.
Colloids and surfaces. B, Biointerfaces, 65(1), 25-29 (2008-04-02)
Adsorption thermodynamic characteristic and kinetics of dissolved chromium from aqueous solutions onto humic acids (HAs) were studied. The results showed that the Freundlich isotherm model described the equilibrium data well. The negative DeltaG degrees confirmed the spontaneity of adsorption process.
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