Skip to Content
Merck
All Photos(1)

Documents

13020

Sigma-Aldrich

Lithium hydroxide monohydrate

purum, ≥98.5%

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
LiOH · H2O
CAS Number:
Molecular Weight:
41.96
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:

grade

purum

Quality Level

Assay

≥98.5%

form

crystalline

impurities

≤1% Li2CO3

pH

12 (0.4 g/L)

anion traces

chloride (Cl-): ≤500 mg/kg
sulfate (SO42-): ≤500 mg/kg

cation traces

Ca: ≤500 mg/kg
Fe: ≤10 mg/kg
K: ≤200 mg/kg
Na: ≤200 mg/kg

SMILES string

[Li+].O.[OH-]

InChI

1S/Li.2H2O/h;2*1H2/q+1;;/p-1

InChI key

GLXDVVHUTZTUQK-UHFFFAOYSA-M

Looking for similar products? Visit Product Comparison Guide

General description

Lithium hydroxide monohydrate is a hydrate of alkali metal hydroxide. Its IR spectral analysis has been reported. A refinement of its crystal structure has been described. Its crystals exhibit monoclinic crystal system and C2/m space group. It can be prepared by reacting Li metal with H2O, followed by the evaporation of the aqueous solution.

Application

Lithium hydroxide monohydrate (LiOH.H2O) may be employed as a catalyst during the melt transesterification of diphenyl carbonate and bisphenol A. Kinetics of this transesterification reaction have been investigated.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Hydrogen bonding. VI. Structural and infrared spectral analysis of lithium hydroxide monohydrate and cesium and rubidium hydroxide hydrates.
Gennick I and Harmon KM.
Inorganic Chemistry, 14(9), 2214-2219 (1975)
Refinement of the crystal structure of lithium hydroxide monohydrate.
Alcock NW.
Acta Crystallographica Section B, Structural Science, Crystal Engineering and Materials, 27(8), 1682-1683 (1971)
Kinetics of melt transesterification of diphenyl carbonate and bisphenol A to polycarbonate with lithium hydroxide monohydrate catalyst.
Kim Y, et al.
Industrial & Engineering Chemistry Research, 31(9), 2118-2127 (1992)
Infrared active vibrational modes of lithium hydroxide monohydrate.
Hase Y.
Inorganic and Nuclear Chemistry Letters, 16(3), 159-163 (1980)
Anupriya Veerman et al.
The Journal of chemical physics, 123(8), 084321-084321 (2005-09-17)
The structures, stabilities, thermodynamic quantities, dissociation energies, infrared spectra, and electronic properties of LiOH hydrated by up to seven water molecules are investigated by using the density-functional theory and the Møller-Plesset second-order perturbation theory (MP2). Further accurate analysis based on

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service