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42860

Sigma-Aldrich

1,5-Diphenylcarbazide

purum p.a., ACS reagent, for the determination of Cd, Cr, Mg, SO4 and others, ≥97.0% (HPLC)

Synonym(s):

1,5-Diphenylcarbohydrazide, sym.-Diphenylcarbazide

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About This Item

Linear Formula:
C6H5NHNHCONHNHC6H5
CAS Number:
140-22-7
Molecular Weight:
242.28
Beilstein:
752039
EC Number:
205-403-7
MDL number:
MFCD00003013
UNSPSC Code:
12352100
PubChem Substance ID:
24866500

grade

ACS reagent
purum p.a.

Assay

≥97.0% (HPLC)

quality

for the determination of Cd, Cr, Mg, SO4 and others

technique(s)

titration: suitable

mp

170-175 °C (lit.)
171-175 °C

SMILES string

O=C(NNc1ccccc1)NNc2ccccc2

InChI

1S/C13H14N4O/c18-13(16-14-11-7-3-1-4-8-11)17-15-12-9-5-2-6-10-12/h1-10,14-15H,(H2,16,17,18)

InChI key

KSPIHGBHKVISFI-UHFFFAOYSA-N

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Other Notes

Reagent for the determination of chromium and other metals

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCBF9703V
BCBD9400V
BCBC9855V
BCBD4680V
BCBC9854V

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K.L. Cheng et al.
Handbook of Organic Analytical Reagents null
Deng-ming Sun
Guang pu xue yu guang pu fen xi = Guang pu, 23(1), 196-198 (2003-08-28)
In this paper, the reaction mechanism of the system of thallium (III)-copper(II)-ethylenediaminete-traacetate-hydrogen peroxide-diphenylcarbazide has been studied by spectrophotometric method. The experimental results show that the reaction mechanism of the system is based on the replacement of copper(II) by thallium (III)
Sivanildo da Silva Borges et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 18(12), 1361-1366 (2002-12-28)
Oxidation of Cr(III) during sonication in carbonated aqueous solutions saturated with CCl4 leads to the quantitative formation of Cr(VI) and provides a simple and rapid method for spectrophotometric chromium determination with 1,5-diphenylcarbazide. The key to this method is the production
B K Semin et al.
FEBS letters, 375(3), 223-226 (1995-11-20)
The interaction of Fe(II) and Fe(III) with the 'high-affinity Mn-binding site' in Mn-depleted photosystem II (PSII) was investigated using diphenilcarbazide (DPC)/2,6-dichlorophenol-indophenol (DCIP) inhibition assay. Fe(III) was ineffective in the inhibition of DPC-DCIP reaction while Fe(II) decreased the rate of DCIP
M D Mamedov et al.
Biochemistry. Biokhimiia, 75(5), 579-584 (2010-07-17)
Transfer of electrons between artificial electron donors diphenylcarbazide (DPC) and hydroxylamine (NH2OH) and reaction center of manganese-depleted photosystem 2 (PS2) complexes was studied using the direct electrometrical method. For the first time it was shown that reduction of redox-active amino
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